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中文摘要：
碳碳不饱和键的双官能团化反应是有机合成的一种重要策略.近年来,利用自由基与氧气对不饱和键的双官能团化反应引起化学家们的广泛关注,并取得了诸多的研究进展.该类反应以氧气为反应试剂,提供了一种绿色、高原子经济性的合成醇或者酮的方法.按自由基类型不同,对近年来在氧气参与下不饱和键的双官能团化反应的研究进展进行综述.
英文摘要：
The difunctionalization of unsaturated carbon-carbon bonds is a powerful strategy for the synthesis of various organic compounds. Recently, the remarkable progress has been made in difunctionalization of unsaturated carbon-carbon bonds with dioxygen and radicals. The present protocol, which utilizes dioxygen as oxygen source, provides a green and atom economy approach to alcohols or ketones. This review will summarize the recent development in this area on the basis of different types of radicals.
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Highly selective copper-catalyzed trifunctionalization of alkynyl carboxylic acids: an efficient rou
Copper-Catalyzed Decarboxylative CN Triple Bond Formation: Direct Synthesis of Benzonitriles from Ph
Cu/Fe-Cocatalyzed Formation of -Ketophosphonates by a Domino Knoevenagel-Decarboxylation-Oxyphosphor
Synthesis of alpha-Ketoamides from Aryl Methyl Ketones and N,N-Dimethylformamide via Copper-Catalyze
Synthesis of esters from aldehydes or carboxylic acids with dichloromethane, dichloroethane or dichl
Synthesis of Primary Amides via Copper-Catalyzed Aerobic Decarboxylative Ammoxidation of Phenylaceti
Sulfonamides Formation from Sodium Sulfinates and Amines or Ammonia under Metal-Free Conditions at A
A catalyst-free, facile and efficient approach to cyclic esters: synthesis of 4H-benzo[d][1,3]dioxin
Copper-Catalyzed Tandem A3-Coupling–Isomerization–Hydrolysis Reactions of Aldehydes and Terminal Alk
Chemoselective Catalytic Reduction of Conjugate a,b-Unsaturated Ketones to Saturated Ketones via Hyd
Transition-Metal-Free Regio-selective Synthesis of Alkylboronates from Arylacetylenes or Vinyl Arene
Cu-Catalyzed Hydrofluoroacetylation of Alkynes or Alkynyl Carboxylic Acids Leading to Highly Stereos
Molecular-oxygen-promoted Cu-catalyzed oxidative direct amidation of nonactivated carboxylic acids w
Cu-catalyzed aerobic oxidative amidation of aryl alkyl ketones with azoles to afford tertiary amides
Sulfonamide formation from sodium sulfinates and amines or ammonia under metal-free conditions at am
b-Ketophosphonates Formation via Deesterification or Deamidation of Cinnamyl/Alkynyl Carboxylates or
Copper-Catalyzed Decarboxylative C-N Triple Bond Formation: Direct Synthesis of Benzonitriles from P
Copper-Catalyzed Oxidative Decarboxylative Arylation of Benzothiazoles with Phenylacetic Acids and &
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