欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
位置：立项数据库 > 立项详情页
中文摘要：
含有与π系统具有非键作用的环蕃化合物近年来成为有机化学和超分子化学的研究热点之一。但是目前分子内这类作用的例子有限。本项目拟通过设计、合成含有最短非键距离的环蕃化合物，填补非键距离空白；同时通过官能团转换，研究分子内有机阴离子或阳离子与π系统的相互作用；通过改变桥链长度，研究这类分子利用阴阳离子与π系统的相互作用对阳或者阴离子进行的分子识别；并且设计合成在一个分子内含有两种不同非键作用的环蕃，这类分子文献中很少报道。本项目旨在研究阴阳离子和中性基团与π系统的相互作用，发现和发展新型阴阳离子受体。因此本项目不仅具有理论意义，而且具有应用前景。
结论摘要：
英文主题词copper catalyst；molecular oxygen；tandem reaction；C-C bond activation；radical reaction
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Highly selective copper-catalyzed trifunctionalization of alkynyl carboxylic acids: an efficient rou
Copper-Catalyzed Decarboxylative CN Triple Bond Formation: Direct Synthesis of Benzonitriles from Ph
Cu/Fe-Cocatalyzed Formation of -Ketophosphonates by a Domino Knoevenagel-Decarboxylation-Oxyphosphor
Synthesis of alpha-Ketoamides from Aryl Methyl Ketones and N,N-Dimethylformamide via Copper-Catalyze
Synthesis of esters from aldehydes or carboxylic acids with dichloromethane, dichloroethane or dichl
Synthesis of Primary Amides via Copper-Catalyzed Aerobic Decarboxylative Ammoxidation of Phenylaceti
A catalyst-free, facile and efficient approach to cyclic esters: synthesis of 4H-benzo[d][1,3]dioxin
Copper-Catalyzed Tandem A3-Coupling–Isomerization–Hydrolysis Reactions of Aldehydes and Terminal Alk
Chemoselective Catalytic Reduction of Conjugate a,b-Unsaturated Ketones to Saturated Ketones via Hyd
Cu-Catalyzed Hydrofluoroacetylation of Alkynes or Alkynyl Carboxylic Acids Leading to Highly Stereos
Molecular-oxygen-promoted Cu-catalyzed oxidative direct amidation of nonactivated carboxylic acids w
Cu-catalyzed aerobic oxidative amidation of aryl alkyl ketones with azoles to afford tertiary amides
Sulfonamide formation from sodium sulfinates and amines or ammonia under metal-free conditions at am
b-Ketophosphonates Formation via Deesterification or Deamidation of Cinnamyl/Alkynyl Carboxylates or
Copper-Catalyzed Decarboxylative C-N Triple Bond Formation: Direct Synthesis of Benzonitriles from P
Copper-Catalyzed Oxidative Decarboxylative Arylation of Benzothiazoles with Phenylacetic Acids and &
beta-Ketophosphonate Formation via Aerobic Oxyphosphorylation of Alkynes or Alkynyl Carboxylic Acids
相关项目
宋秋玲的项目