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聚季铵盐强化超滤分离铼(Ⅶ)
  • ISSN号:1005-9954
  • 期刊名称:化学工程
  • 时间:2012
  • 页码:23-27
  • 分类:TQ028.8[化学工程]
  • 作者机构:[1]湖南科技大学化学化工学院,湖南湘潭411201
  • 相关基金:国家自然科学基金资助项目(20976040,21006022);湖南省科技计划资助项目(2009SK3036)
  • 相关项目:定向嵌段共聚制备温度和pH双重敏感聚氨酯基智能材料
中文摘要:

以聚季铵盐-6强化超滤技术分离铼(Ⅶ),考察聚季铵盐与金属质量比W、pH值、外加盐、运行时间和操作压力对铼截留系数R和膜通量J的影响,结果表明:当加从1增大到7时,R迅速递增,W达到7时的R为0.995,继!增大W,R逐渐趋于1;J随w增大略有下降;当pH值从3增大到8时,R和J几乎不随pH值变化而变化;随着外加盐质量浓度递增,R逐渐递减至不变,J略有下降;随着运行时间延长,R基本不变,J轻微衰减;当操作压力增大时R不变,J呈线性快速递增。研究铼(Ⅶ)-聚季铵盐体系的超滤浓缩行为,控制加=7,pH=7,温度25℃和压力60kPa。当体积浓缩因子为40时,J仅衰减20.1%,在浓缩过程中尺均接近1,截留液铼质量浓度从5mg/L增大j198.3mg/L,渗透液铼质量浓度约为0.04mg/L,铼被有效浓缩。

英文摘要:

Polymer-enhanced ultrafiltration was investigated for the separation of rhenium (Ⅶ) from aqueous solution with the help of polyquatemium-6. The effects of polyquatemium/metal mass ratio w, pH value, the added salt, operating time and pressure on rhenium rejection coefficient R and membrane flux J were studied. The results show that when w increases from 1 to 7, R increases significantly. R value is 0.995 when w = 7. If w is above 7, R is close to 1, and does not change any more. J decreases slighdy with increasing w. When pH value increases from 3 to 8, R and J do not vary with pH. R decreases gradually and then does not change with increasing the mass concentration of the added salt. J declines slightly with the mass concentration of the salt. With increasing the operating time, R is basically kept unchanged, and J decreases slightly. With increasing the operating pressure, R does not change and J increases linearly. Furthermore, the concentration experiment was carried out under the condition of w = 7, pH = 7, temperature 25 ℃ and pressures 60 kPa. When volume concentration factor reaches 40, J only declines 20.1% and R is close to 1. The rhenium mass concentration in the retentate increases from 5 mg/L to 198.3 mg/L, whereas rhenium mass concentration in the permeate is always about 0.04 rag/L, i. e. rhenium (Ⅶ) is concentrated efficiently.

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期刊信息
  • 《化学工程》
  • 中国科技核心期刊
  • 主管单位:中国华陆工程科技有限责任公司
  • 主办单位:中国华陆工程科技有限责任公司
  • 主编:程惠亭
  • 地址:陕西省西安市高新技术产业开发区唐延南路7号 华陆大厦
  • 邮编:710065
  • 邮箱:chem_eng@chinahualueng.com
  • 电话:029-87989701 27988823/4/6
  • 国际标准刊号:ISSN:1005-9954
  • 国内统一刊号:ISSN:61-1136/TQ
  • 邮发代号:52-52
  • 获奖情况:
  • 第六届全国石油和化工行业优秀期刊一等奖,历届陕西省科学技术类优秀期刊,首届《CAJ-CD规范》执行优秀期刊奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),波兰哥白尼索引,荷兰文摘与引文数据库,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:11323