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纳米碳管负载铂的修饰电极对H2O2的测定
  • ISSN号:1000-0720
  • 期刊名称:《分析试验室》
  • 时间:0
  • 分类:TQ463[化学工程—制药化工]
  • 作者机构:Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou, Zhejiang 310028, China, Rowan University, Glassboro, NJ 08028-1701, USA
  • 相关基金:Project supported by the National Natural Science Foundation of China (No. 29975024);Zhejiang Province Natural Science Foundation;Instrumental Analysis Foundation
中文摘要:

A composite polymer carbon fiber electrode modified with Nafion and cellulose acetate is described.The modified electrode discriminates against both anionic reactants and big molecular organic compounds.The bilayer configuration is prepared in two steps.First,the carbon fiber electrode is coated with Nafion,then followed by air evaporation of the solvent,the electrode is dipped in a cellulose acetate solution and hydrolyzed for a selected time.The permeability of the film is explored by use of rotating disk electrode measurements.Parameters affecting the film electrochemistry are investigated.The resulting electrodes show high selectivity and stability in body fluids.For in-vivo voltammetry,the composite polymer modified electrode has been used for detection of the oxidative current of neurotransmitter dopamine in rat brain,while it inhabits the oxidation of anionic neurotransmitter metabolites and some electroactive compounds.

英文摘要:

A composite polymer carbon fiber electrode modified with Nafion and cellulose acetate is described. The modified electrode discriminates against both anionic reactants and big molecular organic compounds. The bilayer configuration is prepared in two steps. First, the carbon fiber electrode is coated with Nation, men followed by air evaporation of the solvent, me electrode is dipped in a cellulose acetate solution and hydrolyzed for a selected time. The permeability of the film is explored by use of rotating disk electrode measurements. Parameters affecting the film electrochemistry are investigated. The resulting electrodes show high selectivity and stability in body fluids. For in-vivo voltammetry, the composite polymer modified electrode has been used for detection of me oxidative current of neurotransmitter dopamine in rat brain, while it inhabits the oxidation of an°C neurotransmitter metabolites and some electroactive compounds.

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期刊信息
  • 《分析试验室》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院 中国有色金属协会
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:analysislab@263.net
  • 电话:010-82013328
  • 国际标准刊号:ISSN:1000-0720
  • 国内统一刊号:ISSN:11-2017/TF
  • 邮发代号:82-431
  • 获奖情况:
  • 综合性分析化学刊物,中文核心期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:25540