中文摘要：

采用静态水热合成法，活性胶液中各组分摩尔比为n（B2O3）／n（Al2O3）／n（P2O5）／n（模板剂）／n（H2O）=r：y：1.5：2：240合成了系列硼铝磷酸盐分子筛BAPO-5。利用XRD,SEM，BET，FT-IR和MAS-NMR等方法对BAPO-5分子筛进行了多角度表征。结果表明，当活性胶液中0〈n（B2O3）／n（Al2O3）〈0.08时，可合成出不同硼含量的BAPO-5，BAPO-5与未添枷杂原子B的AlPO4-5具有相同的晶体结构；BAPO-5的比表面积和比孔容均随B含量的增加而增大，表明BAPO-5中的硼为分子筛的骨架阳离子元素；BAPO-5骨架中的A1和P的配位环境为AlO4和PO4，杂原子B的引入并未引起分子筛的骨架阳离子元素Al和P的配位环境和结构类型的改变；此外，合成的BAPO-5具有规整的六方棱柱晶体外形。

英文摘要：

A series of boron aluminophosphate molecular sieves （BAPO-5） were synthesized by static hydrothermally method using the gel composition n（B2O3）/n（Al2O3）/n（P2O5）/n（Et3N）/n（H2O）=r：y：1.5：2：240. Based on the synthesized BAPO-5 molecular sieves, many of characterization was carried out by XRD, SEM, BET, FT-IR, MAS-NMR methods. It shows that the series of boron aluminophosphate molecular sieves with different boron contents are prepared in the range of 0〈n（B2O3）/n（Al2O3）〈0.08. And the crystal structure of BAPO-5 molecular sieves is attributed to the AFI structure type, which is the same as AlPO4-5. With the increase of the boron content, BET surface area and pore volume of BAPO-5 molecular sieves are also increased. This provides evidence of boron as heteroatom in the framework of BAPO-5 molecular sieves. It is observed that coordination environments of Al and P in the framework of BAPO-5 are AlO4 and PO4. Therefore, AlPO4-5 framework-incorporated B atoms brings no change of coordination environments of AI and P and structure type of BAPO-5 molecular sieves. In addition, SEM images show that the synthesized BAPO-5 molecular sieves have a regular hexagonal prism morphology.