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中文摘要：
利用溶剂热的方法将Cp2TiCl2（Cp=η^5-C5H5）与2，6-吡啶二羧酸钠（L）反应，不同的反应时间得到了2个具有不同晶体空间群的化合物Cp2TiL（1a和1b），而在常温或低温下，Cp2TiCl2或CpTiCl3同羧酸盐或亚胺反应却得到了双核或四核氧桥联的钛化合物。
英文摘要：
Four titanium complexes of Cp2TiL （1a and 1b）, Cp2Ti2Cl2（μ-O） （2）, Cp4Ti4Cl4（μ-O）4 （3） （Cp=η^5-C5H5, L=2,6-dipicolinate） have been synthesized and structurally characterized by X-ray diffraction single crystal structural analysis. The crystal structure of complex 1a has the same chemical formula and different space group with that of complex of lb. The molecule of 2 or 3 has a dimeric or tetrameric structure connected by a μ-O ligand, respectively, and the titanium atoms are surrounded by one Cl atom and one O atom. CCDC： 609318, 1a; 609319, 1b; 609320, 2; 609321, 3.
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