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中文摘要：
含硫族有机过渡金属配位化学是现代化学研究的一个热点，本项目系统研究不同过渡金属半夹心结构含硫族配位化合物的合成，探索硫族化合物的形成规律，提出含硫族元素过渡金属化合物的一般合成方法，研究有机过渡金属多硫族元素化合物中的硫（硒、碲）环与亲核试剂反应，形成硫族元素作为桥基的多核过渡金属化合物。并研究炔烃插入到多核化合物中形成硫烯烃的插入反应。以二硫族元素取代的碳硼烷作为配体与半夹心结构过渡金属反应，形成 16-电子体系的化合物 Cp*M(E2C2B10H10)(E=S, Se, Te; M=Co, Rh, Ir, Ru, Fe)。并研究它们与低价态过渡金属化合物的反应，探讨他们在不同金属-金属之间形成金属键的规律，以此来指导形成金属键多核含硫族元素配合物的方法。利用16-电子体系化合物作为构筑体与不同的含硫族配体作用，形成大环金属或配位大分子化合物，研究这类化合物的光、电、磁性能，开发它们的应用。
结论摘要：
英文主题词Chalcogen, Coordination Chemistry, Organometallic Complexes, Insertion Reaction, Coordination Polymer
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期刊论文
Bimetallic nickel complexes of trimethyl phenyl linked salicylaldimine ligands: Synthesis, structure
Synthesis and characterization of binuclear half-sandwich metal (Co, Ir and Ru) complexes containing
Binuclear neutral nickel complexes bearing bis(bidentate) salicylaldiminato ligands: Synthesis, stru
Binuclear half-sandwich cobalt(III) and rhodium(III) ortho-carboranedichalocogenolato complexes with
A trinuclear silver(I) functionalized N-heterocyclic carbene complex and its use in transmetalation:
Synthesis and crystal structures of titanium complexes: Cp2TiL, Cp2Ti2Cl2(mu-O) and Cp4Ti4Cl4(mu-O)(
Preparation of nano-polyethylene fibers by SBA-15-supported half-sandwich titanium(IV) aryloxy catal
Synthesis and structural characterization of macrocyclic half-sandwich rhodium(III) and iridium(III)
Olefin polymerization behavior of the cyclopentadienyl cobalt complexes bearing pendant sulfur or ox
A route to multi-clusters containing half-sandwich Rh and Ir complexes of chelating 1,2-dicarba-clos
Synthesis and structure of heterometallic complexes (RhFe, CoFe) containing bridging 1,2-dicarba-clo
Nickel (II) complexes with beta-enaminoketonato chelate ligands: Synthesis, solid-structure characte
Stepwise formation of molecular rectangles of half-sandwich rhodium and ruthenium complexes containi
Nickel complexes and cobalt coordination polymers with organochalcogen (S, Se) ligands bearing an N-
Syntheses and molecular structures of 18/16-electron half-sandwich iridium(III) complexes with chela
Self-assembly of trinuclear half-sandwich metal (Co and Ru) complexes containing ancillary ortho-car
Synthesis and molecular structure of hetero-metallic cluster CPCoW(CO)(2)(S2C2B10H10)(2) and binucle
Template-controlled topochemical photodimerization based on "organometallic macrocycles'' through si
Syntheses and structures of half-sandwich iridium(III) and rhodium(III) complexes with organochalcog
Helical supramolecular assemblies of {2,4,6-[Cp*Rh(E-2-1,2-C2B10H10)-(NC5H4CH2S)](3)(triazine)} (E =
Multinuclear self-assembly via half-sandwich complexes Cp* M[S2C2(B10H10)] and pyridine-based ligand
Synthesis and characterization of half-sandwich metal complexes [Cp*M(Tm-Me)]Cl (M=Ir, rh; Tm-Me=tri
Synthesis and characterization of half-sandwich rhodium complexes containing 1,2-dithiolato carboran
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Cont
Synthesis and structures of binuclear half-sandwich cobalt (III) ortho-carboranedithiolato complexes
Functionalized N-heterocyclic carbene iridium complexes: Synthesis, structure and addition polymeriz
Stepwise formation of metallo-prisms of iridium and rhodium complexes bearing pentamethylcyclopentad
Synthesis, characterization, and electrochemical properties of molecular rectangles of half-sandwich
Half-sandwich rhodium complexes containing both N-heterocyclic carbene and ortho-carborane-1,2-dithi
Synthesis and characterization of heterometallic M-Ru (M = Co, Rh, Ir) clusters containing the nido-
Synthesis, structure and transmetalation of N-heterocyclic carbene complex of silver. Evidence of ha
Syntheses, characterization, and ethylene polymerization of titanium and zirconium complexes with [N
Synthesis and characterization of molecular rectangles of half-sandwich p-cymene ruthenium complexes
Synthesis and characterization of heterometallic Rh/Ru complexes supported by 1,2-dichalcogenolato-o
Half-sandwich chromium(III) complexes bearing beta-ketoiminato and beta-diketiminate ligands as cata
Synthesis, characterization and olefin polymerization of the nickel catalysts supported by [N,S] lig
Stepwise formation of organometallic macrocycles, prisms and boxes from Ir, Rh and Ru-based half-san
Synthesis, characterization of novel half-sandwich iridium and rhodium complexes containing pyridine
Trinuclear Rh2M complexes (M = Ni, Pd) bridged by butyl selenolato and carborane diselenolato ligand
Novel nickel(II) and copper(II) complexes with phenoxy-imidazole ligands: Syntheses, crystal structu
Construction of trinuclear iridium clusters through ancillary ortho-carborane-1,2-diselenolato ligan
Polymerization of methyl methacrylate catalyzed by nickel complexes with hydroxyindanone-imine ligan
Stepwise formation of tetra- and hexanuclear iridium and rhodium complexes containing oxalato Ligand
Synthesis and molecular structure of hexanuclear organotitanium ion complex: [Cp ' Ti-6(6)(mu(3)-O)(
Binuclear iridium complexes containing bridging 1,2-dicarba-closo-dodecaborane-1,2-dichalocogenolato
A facile and general approach to the Rh-M (M = Co, Rh) single bond supported by ortho-carborane-1,2-
Synthesis and characterization of half-sandwich Ir and Ru complexes containing Mnt ligand (Mnt = mal
Formation of direct metal-metal bonds from 16-electron "pseudoaromatic" half-sandwich complexes Cp '
Synthesis, crystal structure and third-order nonlinear optical properties of the hetero-metallic clu
Synthesis, characterization, and ethylene polymerization of group IV metal complexes with mono-Cp an
Synthesis and characterization of hetero-binuclear Co-Rh complexes [(CPCoS2C2)-Co-*(B9H10)][Rh(COD)]
Preparation and structure of mono- and binuclear half-sandwich iridium, ruthenium, and rhodium carbe
Syntheses and structures of heterometallic clusters by the reaction of o-carboranyl cobaltadichalcog
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