中文摘要：

本文通过燃烧法在700～850℃制备了CaMoO4：Tb^3＋固溶体发光材料。研究了反应温度与粉末的结构、粒径以及发光性质之间的关系。同时也探讨了材料的优化工艺条件，即最佳燃烧温度为800℃，燃烧5rain，最佳Ca^2＋与Tb^2＋的物质的量比为1：0．05左右。所得CaMoO4：Tb^3＋材料在295nm处近紫外光激发下发射出较强的544nm处的绿色光，对应于Tb^3＋的^5D4-^7F5跃迁。由于配位场对Tb^3＋的微扰导致544nm处的发射峰产生了Stark分裂。

英文摘要：

Abstract：Solid solution luminescent materials CaMoO4： Tb^3＋ were prepared by combustion method at 700-850℃C. The structure, particle size of powder and luminescent properties with the reaction temperature was studied. The optimization of process conditions of materials were as follows： the best combustion temperature is 800 ℃ and the burning time is 5 min ; the ratio of Ca^2＋ to Tb^3＋ is optimized as about 1 ： 0. 05. When excited with 295 nm, emission spectrum of CaMoO4 ： Tb^3＋ showed green fluorescence at 544 nm corresponding to the 5D4-7F5 transition of Tb^3＋. The splitting of the 544 nm emission peak is due to the perturbation of coordination filed for Tb^3＋ lead to Stark splitting.