为了研究活性自由基共聚物的组成、平均段长、链段分布及各元组浓度等重要结构量,本文运用Monte Carlo模拟方法设计一个计算机程序,模拟具有休眠-活化过程的活性自由基共聚过程,并分析所得到的链结构及微结构相关参数,确定了反应参数和聚合物产物结构的关系。
In order to study the important information of living/controlled radical copolymer s microstructure such as composition ratio, average segment length,segment length distribution and sequence concentration,a computer program has been designed by using Monte Carlo method based on a new model of living/controlled copolymerization to simulate the process of the living/controlled radical copolymer analyze the obtained chain s structure and microstrueture s parameters,and ascertain the relationship between the re...