针对桌锌冶炼厂高酸浸出渣含银高的特点,采用硫酸化焙烧-水浸脱锌铁-氯化浸银-冷却结晶PbCl2-铅片置换沉银工艺,对高酸浸出锌渣进行了回收银研究。结果表明,锌和铁的浸出率分别达到92.66%和94.67%,浸出液返回炼锌主流程生产电锌;银和铅的浸出率分别达到94.17%和97.89%;用铅片置换得到粗银粉,银置换率达到99%以上。
Zinc acid-leaching residue contains silver of high grade, so the process of sulphation roasting-remove zinc and iron by water leaching-chlorination leaching silver - cooling - crystallization PbCl2 - cementation silver with lead is used to extracting silver from it. The results indicate that leaching rate of zinc and iron is 92.66% and 94. 67% separately, leach liquor retain to main process. Leaching rate of silver and lead is 94. 17% and 97.89% separately. Coarse silver powder is prepared by lead-cementation-and cementation rate is higher than 99%.