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强碱性阴离子交换树脂去除水中硝氮的动力学研究
  • ISSN号:1674-3075
  • 期刊名称:《水生态学杂志》
  • 时间:0
  • 分类:X502[环境科学与工程—环境工程]
  • 作者机构:[1]厦门理工学院环境科学与工程学院,福建厦门361024, [2]中国科学院城市环境研究所,福建厦门361021
  • 相关基金:国家自然科学基金项目(No.51378446); 福建省自然科学基金项目(No.2013J01211); 厦门市科技计划项目(3502Z20131157)
中文摘要:

选择新型强碱性阴离子交换树脂Amberlite IRA 402和Amberlite IRA 900,与201×7(717)树脂对比,进行吸附去除水中硝氮的实验研究。通过拟合3种树脂的控速步骤和动力学模型,研究吸附过程的动力学行为,并考虑了不同初始浓度的硝酸盐溶液、温度、溶解性有机质(DOM)、pH和转速等的影响。结果表明,IRA 402树脂对硝氮的吸附效果最好(吸附率99.3%),717次之(吸附率98.2%),IRA900稍弱(吸附率93%),但相差不大,且IRA402比较适合去除高浓度DOM废水的硝氮,没食子酸对硝氮去除的影响高于单宁酸。3种树脂吸附硝氮的过程主要受化学反应控制,并符合准二级动力学方程。温度的变化对3种树脂吸附硝氮的行为影响不是很大,可以选择在室温下(25℃)进行。在pH 7.0时,3种树脂吸附硝氮的效果最好,树脂吸附硝氮的转速可设置为200 r/min。

英文摘要:

Ion exchange adsorption is the most effective and promising means of removing nitrate from water at low cost and high practicability. Anion exchange resins,in particular,are characterized by high chemical stability and near 100% removal efficiency. In this study,nitrate nitrogen adsorption experiments were carried out using three strong base anion-exchange resins( two new American products,Amberlite IRA 402 and Amberlite IRA 900,and a Chinese product,201 × 7( 717)) to investigate adsorption kinetics. The rate-determining step was identified and data was fitted to kinetic models. The effects of initial nitrate concentration,temperature,dissolved organic matter( DOM),p H and rotational speed on adsorption were studied to find the most effective resin and the optimal conditions for removing nitrate nitrogen from water. Adsorption kinetic experiments on the three resins were carried out at room temperature( 298K) and an initial KNO3 concentration of 10 mg / L. Solutions were sampled at selected times to monitor nitrate concentration during the adsorption experiments. The nitrate adsorption rate of each resin( IRA402,IRA 900 and 717) was initially high and then declined until equilibrium was established. IRA 402 resin reached equilibrium after 1 hour,with an adsorption efficiency of 99. 3% and an equilibrium absorption capacity for nitrate of 0. 2484 mg / g; 717 resin reached equilibrium after 1. 5 h,with an adsorption efficiency of 98. 2% and an equilibrium absorption capacity of 0. 2456 mg / g; IRA 900 reached equilibrium after 2 h with an adsorption efficiency of 93% and equilibrium absorption capacity of 0. 2326 mg / g. The adsorption kinetics of the three resins was well described by a pseudo-second-order model. The equilibrium absorption capacities of all three resins increased significantly with KNO3 concentration,up to 30 mg / L. The maximum saturation adsorption capacity of nitrate for IRA402,717 and IRA 900 were,respectively,0. 4934 mg / g,0. 4898 mg / g and 0. 4621 mg / g. Furthermore,I

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期刊信息
  • 《水生态学杂志》
  • 中国科技核心期刊
  • 主管单位:中华人民共和国水利部
  • 主办单位:水利部中国科学院 水工程生态研究所
  • 主编:常剑波
  • 地址:武汉市武昌雄楚大街578号
  • 邮编:430079
  • 邮箱:sstx@mail.ihe.ac.cn
  • 电话:027-82926630
  • 国际标准刊号:ISSN:1674-3075
  • 国内统一刊号:ISSN:42-1785/X
  • 邮发代号:38-76
  • 获奖情况:
  • 中国水产核心期刊,湖北省一级优秀期刊,水利部优秀期刊,自然科学核心期刊
  • 国内外数据库收录:
  • 中国中国科技核心期刊,中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:3619