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中文摘要：
研究了以二-（3-吲哚基）-4-氯苯基-甲烷（BICBM）为新的配体与α-溴代异丁酸乙酯（Ebrib）／溴化亚铜（CuBr）组成的催化体系引发甲基丙烯酸甲酯的溶液聚合反应，考察了温度、溶济及配体用量对反应速率以及反应“控制性”等的影响，发现在80℃Ebrib／CuBr／BICBM能较有效地控制甲基丙烯酸甲酯（MMA）的溶液ATRP反应，而且在复合溶剂（环己酮＋DMF）中能更好地控制MMA的“活性”自由基聚合，所得的聚合物分子量分布较窄（1．20～1.50）。
英文摘要：
The solution ATRP of MMA initiated by ethyl a-bromoisobutyrate （Ebrib）/CuBr/ bis（3-indole）-（4-chloro-benzene）-methane （BICBM） was studied in detail. The effect of temperature, solvent and amount of ligand to the ＇controlability＇ of polymerization was investigated. In the condition of Ebrib/CuBr/BICBM at 80 ℃ can realized the ATRP of MMA, furthermore in the mixture solvent（cyclohexanone ＋DMF） may well control the ‘living’ radical polymerization of MMA.
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