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中文摘要：
可控自由基聚合和活性开环聚合可以通过机理转换有效结合，制备出多种结构新颖的共聚物，因此得到广泛关注。本文主要综述三种常见的可控自由基聚合，即原子转移自由基聚合（ATRP）、可逆加成．断裂链转移聚合（RAFT）和稳定自由基聚合（SFRP）与活性开环聚合（ROP）之间进行机理转换，进而制备精细结构共聚物的研究进展。
英文摘要：
Controlled radical polymerization and living ring-opening polymerization can be combined by mechanism transformation to synthesize various copolymers with novel well-defined macromolecular architectures. This method has received much attention. This article summarizes recent research progress on the preparation of well-defined copolymers by mechanism transformation between controlled radical polymerizations, including atom transfer radical polymerization （ATRP） , reversible addition-fragmentation transfer （RAFT） polymerization, and stable free-radical polymerization （SFRP） , with living ring-opening polymerization（ROP）.
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