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Influence of plasma condition on carbon nanotube growth by rf-PECVD
  • 时间:0
  • 分类:TB383.1[一般工业技术—材料科学与工程] TQ127.11[化学工程—无机化工]
  • 作者机构:Advanced Materials Laboratory, Department of Materials Science and Engineering, Tsinghua University
  • 相关基金:financial support by the National Natural Science Foundation of China(grant No:10675070.50701026);the National Basic Research Program of China(973 program,2007CB936601)
中文摘要:

Carbon nanotubes(CNTs)have been synthesized from Ar-CH4 mixtures using rf-plasma enhanced chemical vapor deposition(rf-PECVD)at 500oC.Reduction gases such as H2 and NH3 were found unnecessary for carbon nanotube formation compared to thermal CVD.The relationship between the growth of CNTs and the plasma condition in PECVD has been investigated by in situ self bias measurement.Plasma conditions were controlled by changing the interelectrode distance,rf power and the applied substrate negative bias.By increasing the interelectrode distance and rf power,the spatial density of CNTs was on a rise as a result of the increase in ions density and self bias.As the applied substrate negative bias increased,the spatial density of CNTs decreased possibly due to the positive ions over bombarding effect.

英文摘要:

Carbon nanotubes (CNTs) have been synthesized from Ar-CH4 mixtures using rf-plasma enhanced chemical vapor deposition (rf-PECVD) at 500 degrees C. Reduction gases such as H-2 and NH3 were found unnecessary for carbon nanotube formation compared to thermal CVD. The relationship between the growth of CNTs and the plasma condition in PECVD has been investigated by in situ self bias measurement. Plasma conditions were controlled by changing the interelectrode distance, rf power and the applied substrate negative bias. By increasing the interelectrode distance and rf power, the spatial density of CNTs was on a rise as a result of the increase in ions density and self bias. As the applied substrate negative bias increased, the spatial density of CNTs decreased possibly due to the positive ions over bombarding effect.

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