以Gd2O3、Eu2O3、H2SO4和NaOH为实验原料,采用水热法合成了Gd2O2SO4:Eu3+亚微米棒。XRD和FT-IR分析表明,前驱体Gd2(OH)4SO4·nH2O通过水热合成和随后的热处理(900℃,2h)能转化成纯相Gd2O2SO4。FE-SEM显示,Gd2O2SO4粉体具有边长500-800nm、长度大于10μm的亚微米棒状结构。PL光谱分析表明,在270nm紫外光激发下,Gd2O2SO4:Eu2+的主发射峰位于618nm,呈现红光发射,归属于Eu3+的。D0→7F2跃迁,其跃迁具有单指数衰减行为,荧光寿命为1.13ms。
Gd2O2SO4 : Eua+ sub-microrods are synthesized by hydrothermal synthesis using Gd2O3, Eu2O3 , H2SO4 and NaOH as starting materials. XRD and FT-IR show that the Gd2 (OH)4SO4·nH2O precursor can be transformed into pure Gd2O2 SO4 phase by hydrothermal synthesis and subsequent heat treatment(900℃ for 2h). FESEM images indicate that the Gd2O2SO4 phosphors are sub-microrods with a side length of 500-800nm and a length of more than 10μm. PL spectra reveals that the strongest red emission peak of Gd2O2 SO4:Eu3+ sub-microrods is located at 618nm under 270nm ultraviolet light excitation, which correspond to the a D0→7F2 transition of Eu3+. And the 5D0→7F2 transition of Eu3+ has a single exponential decay behavior with a corresponding lifetime of 1.13ms.