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表面活性剂对钴矿石生物浸出的影响
  • ISSN号:1005-3026
  • 期刊名称:东北大学学报(自然科学版)
  • 时间:2015
  • 页码:814-818
  • 分类:TF18[冶金工程—冶金物理化学]
  • 作者机构:[1]东北大学材料与冶金学院,辽宁沈阳110819
  • 相关基金:国家自然科学基金资助项目(51174062,51374066,51304047); 国家高技术研究发展计划项目(2012AA061501); 国家科技支撑计划项目(2012BAE06B05)
  • 相关项目:细菌与卡林型金矿石碳质物键合作用和抑制劫金机理研究
作者: 刘伟|杨洪英|
中文摘要:

研究了表面活性剂Tween-20,Tween-80与RB-1181对钴矿石生物浸出的影响.研究结果表明:添加表面活性剂使溶液与矿物的接触角显著减小,溶液对矿物表面的润湿作用增强;当质量浓度小于0.25 g/L时,表面活性剂对细菌的生长没有不利影响,添加表面活性剂试样与空白试样的亚铁离子均在72 h内被氧化完全;添加表面活性剂能够改变中间产物S的表面性质,促进细菌对S的氧化,加速矿物表面钝化层的溶解.进而矿物溶解加速,金属浸出率提高.在矿浆质量分数为10%,浸出温度为45℃,转速为180 r/min的条件下,加入表面活性剂后,钴浸出率可提高34%以上,铜浸出率提高15%以上,强化效果显著.

英文摘要:

The effects of Tween-20,Tween-80 and RB-1181 surfactants on the bioleaching of cobalt ore were investigated. The results showed when the surfactant was employed,the contact angle between the solution and mineral was significantly decreased and the wetting action of the solution to the surface of ores increased. In addition,there were not negative effects on the growth of bacteria in the presence of appropriate concentrations of surfactants with the mass concentration of 0. 25 g / L,and the oxidation rates of ferrous ions were the same which were fully oxidized within 72 hrs with or without surfactants. When surfactants were added,the surface properties of the intermediate product element sulfur were changed and the dispersion of surface passivation element sulfur was enhanced,thus the oxidation of element sulfur by bacteria was improved. As a result,the dissolution of the cobalt ore was accelerated,and the leaching efficiencies of metals were improved. In the presence of surfactants,the leaching efficiency of cobalt increased by approximately 34%,and that of copper increased by approximately 15% under the condition with ore pulp concentration of 10%,leaching temperature of 45 ℃ and the rotation rate of 180 r / min.

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期刊信息
  • 《东北大学学报:自然科学版》
  • 中国科技核心期刊
  • 主管单位:中华人民共和国教育部
  • 主办单位:东北大学
  • 主编:汪晋宽
  • 地址:沈阳.南湖
  • 邮编:110819
  • 邮箱:
  • 电话:024-83687378
  • 国际标准刊号:ISSN:1005-3026
  • 国内统一刊号:ISSN:21-1344/T
  • 邮发代号:8-120
  • 获奖情况:
  • 全国优秀科技期刊二等奖,教育部优秀高校自然科学学报一等奖二次,获原冶金部科技期刊质量评比一等奖三次,中国期刊方阵“双百”期刊
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  • 被引量:23296