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In situ characterization of natural pyrite bioleaching using electrochemical noise technique
  • ISSN号:1005-2518
  • 期刊名称:《黄金科学技术》
  • 时间:0
  • 分类:O643.36[理学—物理化学;理学—化学] TG174.36[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:School of Metallurgy, Northeastern University, Shenyang 110819, China
  • 相关基金:Acknowledgements This work was financially supported by the National Natural Science Foundation of China (Nos. 51304047 and 51374066) and the Ph.D. Programs Foundation of the Ministry of Education of China (No. 20130042120040).
中文摘要:

一在里面称为电气化学的噪音(ECN ) 的 situ 描述技术被用来调查自然黄铁矿的 bioleaching。ECN 实验在四个活跃系统被进行(硫磺的酸,铁离子, 9k 文化媒介,和 bioleaching 解决方案) 。ECN 数据在时间和频率领域被分析。光谱从力量获得的噪音阻抗系列光谱为不同系统的密度(PSD ) 阴谋被比较。反应机制也根据试验性的数据分析被建议。bioleaching 系统展出 0.101 M 的最低噪音抵抗。自然黄铁矿的 bioleaching 被认为是简历电池反应,它把它与化学氧化反应区分开来在铁离子并且文化媒介(9k ) 答案。黄铁矿的腐蚀在 bioleaching 的长期的测试以后随着时间的过去变得更严重。

英文摘要:

An in situ characterization technique called electrochemical noise(ECN) was used to investigate the bioleaching of natural pyrite.ECN experiments were conducted in four active systems(sulfuric acid,ferric-ion,9k culture medium,and bioleaching solutions).The ECN data were analyzed in both the time and frequency domains.Spectral noise impedance spectra obtained from power spectral density(PSD)plots for different systems were compared.A reaction mechanism was also proposed on the basis of the experimental data analysis.The bioleaching system exhibits the lowest noise resistance of 0.101 MΩ The bioleaching of natural pyrite is considered to be a bio-battery reaction,which distinguishes it from chemical oxidation reactions in ferric-ion and culture-medium(9k) solutions.The corrosion of pyrite becomes more severe over time after the long-term testing of bioleaching.

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期刊信息
  • 《黄金科学技术》
  • 主管单位:中国科学院
  • 主办单位:山东黄金集团有限公司 中国科学院资源环境科学信息中心
  • 主编:陈玉民
  • 地址:兰州市天水路8号
  • 邮编:730000
  • 邮箱:Hjkx@126.ac.cn
  • 电话:0931-8277791
  • 国际标准刊号:ISSN:1005-2518
  • 国内统一刊号:ISSN:62-1112/TF
  • 邮发代号:54-123
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:3384