对赣江上游河水中主要离子的水化学特征进行研究,结果显示:Ca/Sr=480-897(均值为717),Mg/Sr=191—296(均值为231),Ca/Na=0.60—2.79(均值为1.19),Mg/Na=0.19—0.66(均值为0.38),Si的浓度在4.06—6.57mg·l^-1之间,赣南流域河水中富集Na^+和K^+,而Mg^2+和Ca^2+含量相对较少,Si的含量较高且变化不大.通过海盐校正分析得出,研究区域内大气降水对河流组分的贡献率为9.90%.根据质量平衡方程模型算出流域主元素的69%来源于硅酸盐岩的风化.硅酸盐岩、碳酸盐岩和蒸发盐岩风化对溶解态锶的贡献率依次为48.3%,27.4%和4.3%.通过对主元素、锶(0.20—0.45μmol·1^-1,平均值0.32μmol·l^-1“)以及锶同位素比值(0.7165—0.7249,平均值为0.721)的综合研究,赣南流域^87Sr/^86Sr与1/Sr呈显著的正相关关系,并且从Mg/Na^+,Ca/Na^+,Mg/Ca,HCO3^-/(HCO;+SO4^2-)和^87Sr/^86Sr的关系图中发现:硅酸盐岩的风化对赣南流域水体的化学组成起主要控制作用,碳酸盐岩次之,蒸发盐岩风化的影响不大,人为活动影响较小,通过锶同位素的平衡方程得出:赣南流域为大气降水和岩石风化的混合型,大气降水对赣江上游^87Sr/^86Sr的贡献率约为9.7%,岩石风化对其贡献率约为90.3%。
In this paper, the twenty-three samples of watersheds in the upriver tributaries of Ganjiang river were selected for integratively analyzing the major element, the dissolved Sr (0. 20--0. 45μmol·1^-1 ), Sr isotope (0. 7165--O. 7249) composition, we can calculate that Ca./Sr =480--897, the mean value is 717, Mg/Sr = 191--296, the mean value of it is 231, Ca/Na = 0. 60--2. 79, the mean value is 1.19, Mg/Na = 0. 19-- 0. 66, the mean value is 0. 38. and find that this watersheds is rich in Na^+K^+, poor in Mg^2+ + Ca^2+ , the concentration of Si is high. According to this analysis , we can calculate that contribution rate of atmosphere to the ratio of the river is 9.90%, and find that the source of the dissolved element of watersheds is mostly from weathering of silicate rock, the carbonate rock is taking the second place , the influence of evaporation salt rock is on the small side. The proportion of source from the weathering of silicate rock , the carbonate rock, evaporated rock for dissolved Sr in the samples is 48.3%, 27.4%, 4. 3%. The research of the proportion of end member finds that the ratio of ^87Sr/^86Sr from atmosphere precipitation is 9.7%, from rock weathering is 90. 3 %. This conclusion is good indication for the study of weathering of small watershed in the subtropics.