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赣南小流域的水文地球化学特征和主要风化过程
  • ISSN号:0254-6108
  • 期刊名称:《环境化学》
  • 时间:0
  • 分类:P641.3[天文地球—地质矿产勘探;天文地球—地质学]
  • 作者机构:[1]首都师范大学资源环境与旅游学院、首都圈生态环境过程重点实验室,北京100037, [2]首都师范大学、教育部三维获取与应用重点实验室,北京100037
  • 相关基金:国家自然科学基金(批准号:40473051和40243020)资助项目.感谢中国科学院贵阳地化所环境地球化学国家重点实验室和中国科学院地理科学与资源研究所,为论文实验提供了仪器的使用,在此向他们致以最诚挚的谢意.
中文摘要:

对赣南花岗岩小流域进行采样、测试及分析,发现其河水含有较低的矿化度,水化学组成以Na^+,Ca^2+,Cl^-和HCO3^-为主,溶解性Si的含量明显较高,代表了典型硅酸盐地区河流的相应化学组成,通过Gibbs图分析,赣南流域大部分地区受大气降水的影响比较显著,“蒸发-浓缩”类型的小流域也较多.根据主成分分析和因子分析的结果,定量地估算了大气中CO2和三类岩石对河水中各种离子的贡献比例.与黄河相比,赣南流域受硅酸盐岩风化作用强烈,但主要影响因素仍是碳酸盐和蒸发盐岩,二者对赣南流域溶解质的贡献率分别为42.8%和29.2%,大气中CO2对河水溶解质的贡献率为21.4%,低于世界平均水平.主要风化反应以岩盐和方解石的溶解为主,Si/(Na^++K)比值较低,说明风化反应在表生环境中进行,其产物是富含阳离子的次生矿物.

英文摘要:

Base on tests and analysis of the samples collected from the small granite watersheds in the southern Jiangxi province, it is found the Ganjiang river and its tributaries have low total dissolved solids and the chemical compositions of river waters on dominated by Na^+ , Ca^2+ , Cl^- , HCO3^- and Si (the water has higher Si concentration), which represents that of the river water from the typical silicate rock areas. According to the Gibbs graph analysis, most watersheds of the southern Jiangxi province are evidently influenced by precipitation, and many watersheds are the type of "evaporation-condensation". On the basis of the principal composition analysis and factor analysis, the contributions of atmospheric CO2 and three types of rock to the total dissolved solids are estimated quantificationally. Being compared with the Yellow River, the watersheds in the southern Jiangxi province are influenced strongly by silicate weathering, but the dominant factors still are carbonates and evaporates, which are responsible for 42.8% and 29.2% of total ion equivalent concentration, and that of atmosphere CO2 is 21.4% which is lower than the average value of the world. The evaporate and calcite dissolution are the primary weathering processes. The low Si/( Na* + K)ratio indicates the weathering reactions take place in superficial environment and its products are cation-rich secondary minerals.

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期刊信息
  • 《环境化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:郭良宏
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjhx@rcees.ac.cn
  • 电话:010-62923569
  • 国际标准刊号:ISSN:0254-6108
  • 国内统一刊号:ISSN:11-1844/X
  • 邮发代号:82-394
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27127