中文摘要：

通过环己亚胺基二硫代甲酸钠与邻菲罗啉和硝酸铋反应，合成了新型的铋金属配合物邻菲罗啉合双（环己亚胺基二硫代甲酸）-硝酸铋的单晶，通过X-射线单晶衍射仪测定了晶体结构，IR，元素分析，1HNMR，13CNMR等技术对结构进行了表征．结果表明该晶体属于单斜晶系，空间群P2（1）／n，晶胞参数为：a=1．1632（2）nm，b=1．4414（3）nm，c=1．7681（3）nm，β=93．893（3）°,Z=4，V=2．9578（10）nm3，Dc=1．796g／cm^-3，Mu=6．281mm，F（000）=1576，R1=0．0439，wR2=0．0930[I≥2σ（I）]，在该配合物中，中心铋原子形成了畸变的加帽五角双锥八配位构型．

英文摘要：

The novel bismuth metal complex 1,10-phenanthroline-bis-（hexamethyleneimine-dithiocarbam- ate）-bismuth nitrate was synthesized by the reaction of sodium hexamethyleneimine-dithioearbamate with phenanthriline and Bi（NOa ）a ＂ 5H20. The single crystals structure was determined by X-ray single crystal diffraction analysis. The complex was characterized by IR spectra, elemental analysis,1 H NMR13 C NMR and so on. The crystal belongs to monoelinie with space group P2（1）/n,a=1.1632（2）nm,b=1.4414（3）nm,c=1.7681（3）nm,β=93.893（3）°,Z=4,V=2.9578（10）nm3,Dc=1.796g/cm^-3,Mu=6.281mm,F（000）=1576,R1=0.0439,wR2=0.0930[I≥2σ（I）]. In the complex,the structure shows a distorted pentagonal bipyramidal geometry with eight-coordination for the central bismuth atom.