合成了两种新型噻唑类双席夫碱,5-噻唑醛缩乙二胺双席夫碱(A)和5-噻唑醛缩1,2-环己二胺双席夫碱(B),通过紫外-可见光谱、红外光谱、1 H-NMR共振谱、元素分析对其进行了结构表征.培养得到了5-噻唑醛缩1,2-环己二胺晶体,经X-射线衍射测定,该化合物属单斜晶系,空间群为P2(1)/n,晶胞参数a=11.091(6),b=17.821(10),5.492(9),β=92.97(6)°,V=305 8(3)3,Z=8.
Two thiazole bis-Schiff bases,thiazole-5-carbaldehyde-ethylenediamine(A)and thiazole-5-carbaldehyde-1,2-diaminocyclohexane(B),were synthesized and characterized by UV-Vis spectra,IR,1H-NMR,and elemental analysis,and the crystal structure of B was obtained.According to X-ray single crystal diffraction,the B belongs to the monoclinic space group P2(1)/n with a=11.091(6),b=17.821(10),5.492(9),β=92.97(6)°,V=3 058(3)3,Z=8.