通过接触法充电、恒压电晕充电,以及开路热刺激放电技术,对充电参数(例如充电电压,充电时间和充电温度等)对聚丙烯蜂窝膜(PP cellular)驻极体的压电性及其热稳定性的影响的研究,并从孔洞型薄膜压电体的材料结构和理论模型出发,讨论了这些参数对其影响的原因,分析了与压电活性密切相关的空间电荷的动态特性.结果表明,合理地优化充电参数,能使这类呈闭合孔洞的聚合物蜂窝膜驻极体的压电性及其稳定性得以改善,为拓宽这类新型压电功能膜应用领域,推动其产业化进程提供了一定的理论和技术依据.
The influence of charging parameters (such as charging voltage, charging time and charging temperature, etc. ) on piezoelectricity and its thermal stability of cellular polypropylene film electrets was studied by means of contact charging and constant voltage corona charging methods and the thermal stimulated discharge technique. The cause of the influence is discussed in connection with the structure and the theoretic model of the cellular piezoelectric film electrets, and its dynamic characteristic of space charge is also analyzed. The results show that the piezoelectricity and its thermal stability of these electrets may be improved by optimizing the charging parameters. It is hoped that this work will be helpful to widen the application of cellular PP and will offer theoretic and technical basis for its industrialization.