通过十八烷基异氰酸酯对氧化石墨烯(GO)进行功能化改性,成功制备了烷基化改性石墨烯(iGO)。通过溶液共混的方式制备了氧化石墨烯/聚丙烯(GO/PP)复合材料和功能化氧化石墨烯/聚丙烯(iGO/PP)复合材料,利用差示扫描量热仪(DSC)分析了iGO/PP和GO/PP复合材料的非等温结晶动力学。结果表明,与GO相比,iGO和PP基体有更好的相容性。采用Ozawa模型和Mo模型均可以很好地描述GO/PP及iGO/PP复合材料的非等温结晶过程。
The isocyanate-treated graphene oxides (iGO) were successfully fabricated by graftingoctadecyl isocyanate onto the surface of graphene oxides (GO) with isoeyanicacid octadecyl ester. Thegraphene oxide/polypropylene (GO/PP) and the functional graphene oxide/polypropylene (iGO/PP)composite materials were prepared by solution blending method. The nonisothermal crystallization kinetics ofiGO/PP and GO/PP composites were investigated by differential scanning calorimeter (DSC). The resultsshow that iGO exhibits a better compatibility with the PP matrix compared with GO. Both Ozawa model andMo model can well describe the nonisothermal crystallization process for GO/PP and iGO/PP composites.