分别通过N-(声-羟基苯基)甲基丙烯酰胺与N-苯基马来酰亚胺、N-苯基甲基丙烯酰胺与N-(p-羟基苯基)马来酰亚胺的共聚合,制备了两种聚合物树脂聚N-(P-羟基苯基)甲基丙烯酰胺共M苯基马来酰亚胺(poly(HPMA—CO—PMI))和聚N-苯基甲基丙烯酰胺共N_(P-羟基苯基)马来酰亚胺(poly(MPA—CO—HPMI)).结果表明,这两种聚合物都是按1:1的摩尔比交替共聚的,它们都具有良好的溶解性、成膜性和亲水性,并且它们的玻璃化温度瓦都在280℃以上.将它们分别与感光剂2,1,5-磺酰氯的衍生物、助剂二苯甲酮等复配成两种紫外正型光刻胶,初步光刻实验表明,其最大分辨率都可以达到1肚m,并且都可以耐270℃的高温.
Two copolymers poly ( (N- (p-hydroxyphenyl)methacrylamide)-co-(N-phenylmaleimide)) poly(HPMI-co-PMA) and poly ( (N phenylmethacrylamide)-co-(N~ (p-hydroxyphenyl) maleimide) ) poly (PMAco-HPMI) were prepared from the copolymerizations of N-(p-hydroxyphenyl) methacrylamide and N-phenylmaleimide, and N-phenylmethacrylamide and N-(p-hydroxyphenyl) maleimide, respectively. It showed that both copolymers were 1 ~ 1 in molar composition and were alternating. Both had good solubility in organic solvent, film-forming characteristics, hydrophilicity, and high glass transition temperature (T〉280℃). As matrix resins, they were mixed respectively with photosensitizer derivative of 2, 1, 5-diazonaphthoquinone sutfochloride (DNS), additive benzophenone, etc. to obtain two UV positive photoresist. Preliminary photolithographic experiments testified that both photoresists had a resolution of no less than 1 μm and a high- thermostability of up to 270℃.