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中文摘要：
合成了一种基于联萘酚的新型手性单体,（S）-3-（二苯羟甲基）-3＇-3-乙烯基-2,2＇-二羟基-1,1＇-联萘（5）.通过由偶氮异丁腈（AIBN）引发的自由基聚合得到聚[（S）-3-（二苯羟甲基）-3＇-3-乙烯基-2,2＇-二羟基-1,1＇-联萘]（P-5）,旋光、紫外-可见光谱、圆二色谱表征结果表明P-5以单手性螺旋结构的形式存在于溶液中.考察了螺旋齐聚物P-5在催化苯甲醛与Danishefsky双烯烃的杂-Diels-Alder（HDA）反应中的不对称诱导作用,所得加和产物的ee值达71%,P-5可以被回收重复使用而保持催化活性不变.
英文摘要：
A novel binaphthol-based monomer, 3-hydroxydiphenylmethyl-3＇-vinyl-2,2＇-dihydroxy-1,1＇-binaphthyl was synthesized and polymerized using azodiisobutyrodinitrile（AIBN） as an initiator to afford the polymer P-5. Polarimetry, UV-Vis and circular dichroism spectroscopy characterizations indicated that the polymer existed in the form of one-handed helical structure in solution. The application of helical polymer P-5 in catalytic asymmetric hetero-Diels-Alder（HDA） reaction between benzaldehyde and Danishefsky＇s diene has been studied, resulting in the target product with 71% ee. P-5 can be easily recovered and reused without loss of catalytic activity.
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