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污水污泥热解试验研究
  • ISSN号:1009-6094
  • 期刊名称:《安全与环境学报》
  • 时间:0
  • 分类:X705[环境科学与工程—环境工程]
  • 作者机构:[1]南开大学环境科学与工程学院,天津300071
  • 相关基金:重点基础研究发展计划项目(2007CB210202);国家自然科学基金项目(50976050)
中文摘要:

研究了热解终温对污水污泥热解产物产率的影响,对污泥热解油中的轻质组分进行了分析,并初步探讨了污泥热解残渣的基本性质。研究表明,热解终温为450~500℃时,液相产物产率较高,随着热解终温的升高,热解残渣减少的趋势与液相产物增加的趋势相似;450℃时得到的污泥热解油的轻质组分中主要含有烷烃类、烯烃类、腈类、含氮杂环化合物和单环芳香烃等;随着热解终温的升高,残渣表面越来越松散和粗糙;450℃时得到的热解残渣孔容积最大,而500℃时得到的残渣微孔最为发达,比表面积值最高。

英文摘要:

In this paper, the effect of final pyrolysis temperature on the yield of products from the pyrolysis of sewage sludge was studied. The light fraction from sludge pyrolysis oil was analyzed. The fundamental properties of the pyrolysis residues were also investigated briefly. The results showed that when the final pyrolysis temperature was between 450 ℃ to 500 ℃ , the yield of liquid product was favorable. With the increase of final pyrolysis temperature, the decreasing trend of pyrolysis residue was similar to the increasing trend of liquid product. Both of them were steep when the temperature was under 450℃ and mild when the temperature was higher than 450 ℃. Meanwhile the uneondensed gas increased snloothly with the increase of final pyrolysis temperature. The light fractions of pyrolysis oil obtained at 450 ℃ was mainly consisted of alkanes, alkenes, nitriles and nitrogen-containing heterocyclic compounds as well as MAHs etc. Among them, the concentration of toluene, 4- methyl-phenol, 1 methyl - 2,5 - pyrrolidinedione, pyridinc, 1 dodecene and pentadecane etc. were significant. The pyroysis residues of sewage sludge contained low carbon and high ash. However, they still possessed some volatile content. With the increase of final pyrolysis temperature, the surface of pyrolysis residue became more and more looser and rougher. The residue obtained at 450 ℃ exhibited highest pore volume. Nevertheless, the residue obtained at 500 ℃ owned maximum specific surface area in respect that it possessed highest number of micropores.

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期刊信息
  • 《安全与环境学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国兵器工业集团公司
  • 主办单位:北京理工大学 中国环境科学学会 中国职业安全健康协会
  • 主编:冯长根
  • 地址:北京市海淀区中关村南大街5号
  • 邮编:100081
  • 邮箱:aqyhjxb@263.net;aqyhjxb@wuma.com.cn
  • 电话:010-68913997
  • 国际标准刊号:ISSN:1009-6094
  • 国内统一刊号:ISSN:11-4537/X
  • 邮发代号:2-770
  • 获奖情况:
  • 获首届《CAJ-CD》执行优秀期刊奖,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:17182