[目的]针对目前土壤可溶性氮的提取方法在提取剂种类、水土比及土样保存状态(新鲜和风干)等方面的不同,分析普通山地红壤可溶性氮不同条件下的提取效率,以期为土壤可溶性氮提取提供试验依据。[方法]利用常绿阔叶林植被下普通山地红壤,分别以其新鲜土和风干土为试验材料,探讨2mol/LKCl和0.5mol/LK2SO4 2种提取剂在水土比4:1、6:1和10:1下提取土壤可溶性氮的差异,研究该类型土壤可溶性氮不同提取条件下的提取效率。[结果]KCl比K2SO。更适合用于提取土壤NHd—N,KCl提取的NH4+-N不仅量大且稳定性好,K2SO4则需在较大水土比下才能充分提取土壤NH4+-N;2种提取剂在NO3- -N提取上的差异性很小,但低水土比下KCl提取NO卜N的稳定性高于K2SO4;两者提取的NO2-N性能非常接近;在土壤SON的提取中,2种提取剂的差异较小,KCl提取的SON量少于K2SO4,但稳定性高于K2SO4二者的SON提取量具有极显著相关性;用K2SO4提取MBN时可以不考虑水土比的影响,但使用KCl则必须慎重选择水土比。提取新鲜样时KCl和K2SO4之间的差异大于提取风干样时的差异,所以在对新鲜样中可溶性氮提取时应更注重提取剂的选择。[结论]该试验结果为提高土壤可溶性氮的提取效率,增加测定结果的可比性奠定了试验基础。
[Objective] The extraction efficiency of soluble nitrogen in common moun- tain red soil under different conditions was analyzed to provide experimental refer- ences for the extraction of soil soluble nitrogen. [Method] The fresh soil and air-dried soil, which were the common mountain red soil under evergreen broad-leaved forest vegetation, were used as the experimental materials. The 2 mol/L KCI and 0.5 mol/L K2SO4 were used as the extractants to extract the soil soluble nitrogen with the extractant-to-soil volume ratio at 4:1, 6:1 and 10:1, respectively, to examine the extrac- tion efficiency of soluble nitrogen in the experimental soil with different extraction conditions. [Result] Compared with K2SO4, the NH4+-N extracted by KCI was better in quantity and stability; while only at high extractant-to-soil volume ratio could K2SO4 fully extract the soil NH4+-N. The 2 extractants showed small difference in extracting NO3--N, but at low extractant-to-soil volume ratio, the stability of NO3--N extracted by KCI was higher than that extracted by K2SO4. The properties of NO2- -N extracted by the 2 extractants were very similar. As for soil SON extraction, there was small dif- ference between the 2 extractants. However, the SON extracted by KCI was fewer in quantity than that by K2SO4, but had higher stability, and the extracted SON amount of the 2 extractants showed significant correlation. The extractant-to-soil ratio had little effect on MBN extraction using K2SO4, but the effect was significant when using KCI to extract MBN. The difference between the extraction efficiency of KCI and K~SO4 in extracting fresh soils was greater than that in extracting air-dried soil; therefore, the extractants should be carefully selected in soluble nitrogen extraction from fresh soil. [Conclusion] The results lay the experimental foundation for improving the extraction efficiency of soil soluble nitrogen and increasing the comparability of measurement results.