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均匀沉淀法制备不同粒径的纳米氧化锌
  • 期刊名称:广东化工
  • 时间:0
  • 页码:422-425
  • 语言:中文
  • 分类:TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]太原理工大学应用化学系,山西太原030024
  • 相关基金:该论文由中国国家自然科学基金项目资助(20773092)
  • 相关项目:界面功对典型高分散多相反应的影响
中文摘要:

由于纳米氧化锌的功能和用途不同,因而需要制备如不同平均粒径的纳米氧化锌。论文以六水硝酸锌为原料,尿素为沉淀剂,研究了均匀沉淀法制备不同平均粒径纳米氧化锌的工艺条件,讨论了工艺条件对其粒径和产率的影响规律。结果表明:通过均匀沉淀法制备的纳米氧化锌的前驱体为Zn5(OH)6(CO3)2;制备的纳米氧化锌为六方晶系的球形颗粒,平均粒径为20-50nm;纳米氧化锌的产率随反应物浓度的增大、反应温度的升高、反应配经(n尿素/Zn2+)的增大而增大;纳米氧化锌颗粒的平均粒径随反应物浓度的减小、反应温度和煅烧温度的降低而减小。

英文摘要:

Because the application purposes of nano-ZnO are different and different average diameters of nano-ZnO is needed. In the paper, process conditions of homogeneous precipitation were investigated to prepare different average diameters of nano-ZnO by the reaction of the Zinc nitrate and urea. And the effects of process conditions on the diameters and yield of nano-ZnO were discussed. The results showed that: the precursor of nano-ZnO was Zns(OH)6(CO3)2; the structure of nano-ZnO was hexagonal system and approximative spherical and the average nano-particle diameters was from 20 nm to 50 nm; the yield of nano-ZnO increased respectively with the increasing of the concentrations of the reactants, with the reaction temperature and with the molar rate of urea to Zinc ion; and nano-ZnO particle size decreased respectively with the decreasing of the concentration of reactant, with the reaction temperature and with calcination temperature.

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