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Study on the volatilization kinetics of lead in carbon-containing pellets made of Zn-Pb-bearing dusts
  • ISSN号:1674-3458
  • 期刊名称:《宝钢技术研究:英文版》
  • 时间:0
  • 分类:TF046.6[冶金工程—冶金物理化学] X74[环境科学与工程—环境工程]
  • 作者机构:[1]Ironmaking Plant, Baoshan Iron & Steel Co., Ltd., Shanghai 200941, China, [2]Metallurgy Department of Metallurgical and Ecological College,University of Science and Technology, Beijing10083, China
  • 相关基金:financially supported by the “Joint Fund(project number U1260202)for Iron and Steel Research”built by the National Natural Science Foundation of China and Baosteel Group Corporation
中文摘要:

This study investigated the volatilization kinetics of lead in pellets made of Zn-Pb-bearing dusts mixed with coal powder,in a nitrogen atmosphere and in the temperature range between 1 100 ℃- 1 300 ℃,and showed that the reduction temperature has a significant effect on the volatilization rate of lead and that neither the particle size of the coal powder nor the extra carbon content has any effect on the volatilization rate. The obtained activation energy for the volatilization of lead is 88. 74 k J / mol. The volatilization rate of lead is controlled by both the lead evaporation reaction and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.

英文摘要:

This study investigated the volatilization kinetics of lead in pellets made of Zn-Pb-bearing dusts mixed with coal powder,in a nitrogen atmosphere and in the temperature range between 1 100 ℃ - 1 300℃ ,and showed that the reduction temperature has a significant effect on the volatilization rate of lead and that neither the particle size of the coal powder nor the extra carbon content has any effect on the volatilization rate. The obtained activation energy for the volatilization of lead is 88.74 kJ/mol. The volatilization rate of lead is controlled by both the lead evaporation reaction and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.

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期刊信息
  • 《宝钢技术研究:英文版》
  • 主管单位:宝钢集团有限公司
  • 主办单位:宝钢集团有限公司
  • 主编:
  • 地址:上海市宝山区富锦路655号
  • 邮编:201900
  • 邮箱:bstr@baosteel.com
  • 电话:021-26648493
  • 国际标准刊号:ISSN:1674-3458
  • 国内统一刊号:ISSN:31-2001/TF
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国剑桥科学文摘
  • 被引量:12