设计合成一系列1,10-菲咯啉衍生物,以2,9-二甲基-4,7-二苯基-1,10-菲咯啉与芳基醛为原料,以醋酸酐为溶剂,在酸的催化下,通过Adole缩合反应,合成了7个(E)-2,9-二芳乙烯基-4,7-二苯基-1,10-菲咯啉的衍生物,产率为50%~68%。该合成方法原料易得,操作简单,收率较高,有很好的应用前景。
A series of 1,10-phenanthroline derivatives were designed synthesized. In this method, 2,9- dimethyl-4,7-diphenyl-1,10-phenanthroline and aryl aldehyde were used as the starting materials, acetic anhydride was used as the solvent, seven 2,9-(E)-diaryl vinyl-l, 10-phenanthroline derivatives were ob- tained by adole condensation with yield 50% -68 % . The method was of readily available raw materials, simple operation, medium and above yield, apply a wide range of substrates.