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Simultaneous desulfurization and denitrification of sintering flue gas via composite absorbent
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:X757[环境科学与工程—环境工程]
  • 作者机构:Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Centre for Simulation and Modelling of Particulate Systems, Southeast University–Monash University Joint Research School
  • 相关基金:Supported by the National Science Foundation of China for Distinguished Young Scholars(No.51325601);Major Program of National Science Foundation of China(No.51390492);Joint Funds of National Science Foundation of China(No.U1560205)
中文摘要:

Experiments on simultaneous absorption of SO2 and NOX from sintering flue gas via a composite absorbent NaClO2/NaClO were carried out. The effects of various operating parameters such as NaClO2 concentration(ms), NaClO concentration(mp), molar ratio of NaClO2/NaClO(M), solution temperature(TR), initial solution pH, gas flow(Vg) and inlet concentration of SO2(CS) and NO(CN) on the removal efficiencies of SO2 and NO were discussed. The optimal experimental conditions were determined to be initial solution pH = 6, TR=55 °C and M = 1.3 under which the average efficiencies of desulfurization and denitrification could reach99.7% and 90.8%, respectively. Moreover, according to the analysis of reaction products, it was found that adding NaClO to NaClO2 aqueous solution is favorable for the generation of ClO2 and Cl2 which have significant effect on desulfurization and denitrification. Finally, engineering experiments were performed and obtained good results demonstrating that this method is practicable and promising.

英文摘要:

Experiments on simultaneous absorption of SO2 and NOX from sintering flue gas via a composite absorbent NaClO2/NaClO were carried out. The effects of various operating parameters such as NaClO2 concentration (m(s)), NaClO concentration (m(p)), molar ratio of NaClO2/NaClO (M), solution temperature (T-R), initial solution pH, gas flow (V-g) and inlet concentration of SO2 (CS) and NO (C-N) on the removal efficiencies of SO2 and NO were discussed. The optimal experimental conditions were determined to be initial solution pH = 6, TR = 55 degrees C and M = 1.3 under which the average efficiencies of desulfurization and denitrification could reach 99.7% and 90.8%, respectively. Moreover, according to the analysis of reaction products, it was found that adding NaClO to NaClO2 aqueous solution is favorable for the generation of ClO2 and Cl-2 which have significant effect on desulfurization and denitrification. Finally, engineering experiments were performed and obtained good results demonstrating that this method is practicable and promising. (C) 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
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  • 被引量:385