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有机污染物和碳纳米颗粒:吸附机理及影响因素
  • ISSN号:1673-565X
  • 期刊名称:《浙江大学学报:A卷英文版》
  • 时间:0
  • 分类:X13[环境科学与工程—环境科学]
  • 作者机构:[1]Faculty of Environmental Science & Engineering, Kunming University of Science & Technology, Kunming 650500, China
  • 相关基金:Project supported by the National Natural Science Foundation of China CNos. 41303093, 41222025, and 41273138), the Program for New Century Excellent Talents in University of Ministry of Education of China, and the Recruitment Program of Highly- Qualified Scholars in Yunnan Province (No. 2010CI 109), China
中文摘要:

研究目的:碳纳米颗粒由于其独特的优良性能被广泛应用,从而不可避免地进入环境。进入环境的碳纳米颗粒与有机污染物有很强的相互作用,并且碳纳米颗粒对有机污染物的吸附可能会影响污染物的环境风险和迁移。因此,本研究总结了目前有机污染物在碳纳米颗粒上吸附的研究进展,为有机污染物及碳纳米颗粒的环境行为研究及风险评价提供重要信息。重要结论:有机污染物和碳纳米颗粒的主要相互作用有憎水性、静电、氢键和π-π作用,这些作用及它们的强度受碳纳米颗粒的表面性质、形态及有机污染物的分子大小、结构和官能团等影响。不同的吸附机理可能同时控制有机物在碳纳米颗粒上的吸附过程,而且在不同的环境条件下吸附控制机理不同。区分吸附控制机理和影响因素的研究对预测有机污染物和碳纳米颗粒的环境行为和风险非常重要。

英文摘要:

Carbon nanoparticles (CNPs) are novel manufactured materials with unique properties and have potential for a variety of applications. Adsorption of organic contaminants by discharged CNPs may affect the fate and transport of organic contaminants in the environment. This review summarizes the present research progress regarding organic contaminant adsorption on CNPs, and provides important information for the evaluation of the environmental behavior of organic contaminants and the risks associated with the use of CNPs. The main adsorption mechanisms involve hydrophobic interactions,π-πinteractions, hydrogen bonds, and electrostatic interactions. These interactions may exist simultaneously, while the controlling adsorption mechanism differs de-pending on the properties of both the organic contaminants and the CNPs along with environmental conditions. The status of CNPs in the environment greatly affects or even controls their characteristics for adsorption of organic contaminants. The mobility and transport of dispersed CNPs and CNP-adsorbed organic contaminants could be promoted in natural aqueous environments, po-tentially increasing the spread of various organic contaminants and their associated environmental risks. Investigating the ad-sorption mechanisms and impact parameters is vital in predicting the environmental behaviors of both organic contaminants and CNPs and their associated risks.

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期刊信息
  • 《浙江大学学报:A卷英文版》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:浙江大学
  • 主编:
  • 地址:杭州浙大路38号,浙江大学学报《英文版》编辑部
  • 邮编:310027
  • 邮箱:jzus@zju.edu.cn
  • 电话:0571-87952276 87952331
  • 国际标准刊号:ISSN:1673-565X
  • 国内统一刊号:ISSN:33-1236/O4
  • 邮发代号:
  • 获奖情况:
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  • 被引量:215