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One-pot synthesis of Bi2Se3 nanostructures with rationally tunable morphologies
  • ISSN号:1674-0068
  • 期刊名称:《化学物理学报》
  • 时间:0
  • 分类:TQ457.29[化学工程—农药化工] TB383[一般工业技术—材料科学与工程]
  • 作者机构:Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Ouantum Matter Physics of Chinese Academy of Sciences, Center of Advanced Nanocatalysis (CAN-USTC) & Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China
  • 相关基金:Acknowledgements This work was supported by Collaborative Innovation Center of Suzhou Nano Science and Technology, MOST of China (No. 2014CB932700), 2015SRG-HSC049, National Natural Science Foundation of China (Nos. 21203173, 21573206, 11574281, 51371164, 51132007, and J1030412), Strategic Priority Research Program B of the CAS (No. XDB01020000), and Fundamental Research Funds for the Central Universities (Nos. WK2340000050, WK2060190025, and WK3510000002).
中文摘要:

形状控制证明了是定制双性人 2 为许多应用程序的 Se 3 nanostructures。这里,三不同双性人 2 Se 3 nanostructures,即,螺线类型 nanoplates,光滑的 nanoplates,和树枝状的 nanostructures,被在合成系统操作过度饱和水平准备。这机制研究显示在低过度饱和,那在生长能引起在双性人 2 Se 3 粒子连续地被增加,导致螺线类型 nanoplates 的形成。在中间的过度饱和,非结晶的双性人 2 Se 3 粒子和随后的再结晶导致了光滑的 nanoplates 的形成。而且在高过度饱和,多晶的双性人 2 开始形成的 Se 3 核心,在哪个双性人 2 Se 3 发生了。这个工作不仅推进我们生长机制的理解而且提供一条新途径控制双性人 2 Se 3 nanostructures。

英文摘要:

Shape control has proven to be a powerful and versatile means of tailoring the properties of Bi2Se3 nanostructures for a wide variety of applications. Here, three different Bi2Se3 nanostructures, i.e., spiral-type nanoplates, smooth nanoplates, and dendritic nanostructures, were prepared by manipulating the supersaturation level in the synthetic system. This mechanism study indicated that, at low supersaturation, defects in the crystal growth could cause a step edge upon which Bi2Se3 particles were added continuously, leading to the formation of spiral-type nanoplates. At intermediate supersaturation, the aggregation of amorphous Bi2Se3 particles and subsequent recrystallization resulted in the formation of smooth nanoplates. Furthermore, at high supersaturation, polycrystalline Bi2Se3 cores formed initially, on which anisotropic growth of Bi2Se3 occurred. This work not only advances our understanding of the growth mechanism but also offers a new approach to control the morphology of Bi2Se3 nanostructures.

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期刊信息
  • 《化学物理学报》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国物理学会
  • 主编:杨学明
  • 地址:合肥中国科学技术大学
  • 邮编:230026
  • 邮箱:cjcp@ustc.edu.cn
  • 电话:0551-3601122
  • 国际标准刊号:ISSN:1674-0068
  • 国内统一刊号:ISSN:34-1295/O6
  • 邮发代号:26-62
  • 获奖情况:
  • 1998年获安徽省优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:4282