中文摘要：

采用无有机模板剂一步法制备了Ru/ZSM-5催化剂，利用X射线衍射、N2吸附-脱附、NH3-程序升温脱附和CO2-程序升温脱附、扫描电镜和透射电镜等方法对催化剂进行了表征.考察了反应温度、钌负载量和催化剂重复利用等因素对Ru/ZSM-5上葡萄糖加氢反应性能的影响，并与浸渍法制备的Ru/ZSM-5催化剂进行了对比.结果表明，与传统浸渍法相比，一步法制备的Ru/ZSM-5催化剂钌粒子具有更高的分散性和稳定性.在120 oC和4 MPa的温和反应条件下，葡萄糖接近完全转化，山梨醇选择性高达99.2%，催化剂可重复利用5次，仍保持较高活性.

英文摘要：

Ru particles were introduced into the zeolite ZSM-5 （MFI） by either a conventional impregnation method or a one-step template-free process. The resultant materials were characterized by X-ray diffraction, N2 adsorption-desorption, scanning electron microscopy, transmission electron micros-copy, NH3 and CO2 temperature-programmed desorption. The results indicated that the Ru species in ZSM-5 catalysts prepared via the latter approach （designated as Ru/ZSM-5-TF） were highly dis-persed in the ZSM-5 framework structure and this material exhibited high catalytic performance during the hydrogenation of D-glucose to D-sorbitol. The conversion of D-glucose was as high as 99.6%with D-sorbitol selectivity reaching 99.2%, exceeding the performance of Ru/ZSM-5 catalysts prepared by the conventional impregnation method with microporous or desilicated ZSM-5 sup-ports. More importantly, this catalyst showed high stability against leaching and poisoning and could be reused several times. The extensive dispersion of the Ru species, strong interaction be-tween the Ru species and the ZSM-5, and the suitable surface acidity-basicity balance of the Ru/ZSM-5-TF were all critical factors leading to excellent catalytic behavior and stability.