研究了以水合肼为还原剂,液相化学还原法制备铜配位聚醮酸乙烯酯(Cu/PVAc)的过程。分析了温度、pH、助剂对铜配位聚酣酸乙烯酯的影响,并用透射电镜和X射线衍射仪对粒子进行了表征,结果显示,在助剂的PVP的作用下,可以得到分散效果较好,平均粒度为25nm的Cu/PVAc颗粒。
Copper eoordination polymer Cu /PVAe was synthesized from CuCI2 by chemical reduction in the liquid phase with hydrazine as the redueing agent in THF system. The dimension and structure were surveyed by TEM and XRD. The result showed that the palieles of Cu/PVAc were dispersed well with the protection of ployvinyl pyrrolidone in the syetem,and the average size was about 25 nm.