通过循环伏安法(CV),计时电流法(CA)和线性扫描法(LSV)对二甲氧基甲烷的电氧化特性进行了研究.发现当用Ho^3+修饰Pt/C催化剂电极后可以大幅度提高电极对DMM的电催化活性.热处理Ho^3+修饰后Pt/C催化剂电极,可进一步提高该电极对DMM的电催化氧化活性.
The electro-oxidation characteristics of dimethoxyrnethane (DMM),which is a possible alternative fuel for direct methanol fuel cell (DMFC),were carried out by cychcvoltammetry (CV) and chronoamperometry(CA) at Pt/C catalyst and the Pt/C electrodes modified with Ho^3+. The eletrocatalytic activities were highly improved after the Pt/C electrodes were modified with Ho^3+ .A new oxidation peak appeared at more negative potential after the heat- treatment of the electrodes modified with Ho^3+ , which made the electrode more active for DMM electrooxidation.