中文摘要：

由氯甲酸乙酯和硫氰酸钠经亲核取代反应和异构化合成N-乙氧羰基异硫氰酸酯中间体,再将该中间体与1,6-己二胺经亲核加成反应,合成N,N’-二乙氧羰基-N’’,N’’’-（1,6-亚己基）双硫脲。对其进行元素分析、红外光谱、核磁共振氢谱及碳谱分析。将所得产物配成溶液,分别与Cu2＋,Ni2＋和Fe3＋溶液混合,用紫外可见分光光度计测定产物溶液吸光度的变化,对产物与Cu2＋离子的沉淀产物进行红外光谱检测,对比产物与其Cu2＋络合物的红外光谱。研究结果表明：具有新型结构的双硫脲可分别与此3种离子发生反应,并表现出对Fe3＋的较强选择性。产物与Cu2＋生成的络合物为环状螯合物。

英文摘要：

The intermediate N-ethoxylcarbonyl isothiocyanate was synthesized from ethyl chloroformate and sodium thiocyanate by nucleophilic substitution reaction and isomerization.Then using this intermediate with 1,6-diaminlhexane as raw materials,the target product N,N＇-diethoxycarbonyl-N＇＇,N＇ ＇＇-（1,6-hexylidene） dithiourea was obtained by nucleophilic addition reaction.The compound was characterized by elemental analysis,infrared spectrum,1HNMR and 13CNMR.The solution of the compound was mixed with Cu2＋,Ni2＋,Fe3＋ solution respectively,and the changes of the absorbance of three compound solutions via UV-Vis spectrophotometer were determined.The precipitate of the compound reacting with Cu2＋ ion was analyzed through infrared spectrum.The results show that this dithiourea with new structure can react with three ions separately,and has a best selectivity to Fe3＋.Compared with the IR spectral data of compound,the structure of the precipitate is of annular chelate.