采用机械球磨加固相烧结法合成Mn3(Cu0.6Si0.15Ge0.25)N/Ag复合材料。在77K-300K温度范围内,分别研究了Mn3(Cu0.6Si0.15Ge0.25)N/Ag复合材料的热膨胀性能,电导性能和热导性能。当含Ag量分别为1,5,10和20wt%时,所有样品在有效的温度区间205K-275K表现出负热膨胀。随着Ag含量的增加,有效温度区间向室温方向移动。另外,和Mn3(Cu0.6Si0.15Ge0.25)N材料相比,Mn3(Cu0.6Si0.15Ge0.25)N/Ag复合材料具有更高的电导率1×10-6(Ohm·m)-1和热导率10.5W/(mK)。
Mn3(Cu0.6Si0.15Ge0.25)N/Ag composites were prepared by mechanical ball milling and sol- id state sintering. The thermal expansion coefficients, electrical conductivities and thermal conductivi- ties of Mn3(Cu0.6Si0.15Ge0.25)N/Ag composites were studied in the temperature range from 77 K to 300 K. All samples with Ag amount of 1, 5, 10 and 20 wt% show negative thermal expansion (NTE) within an effective temperature range from 205 K to 275 K. It is interesting to find that the effective temperature range of NTE moves toward room temperature and becomes narrower with the increase of Ag content. Furthermore, Mn3(Cu0.6Si0.15Ge0.25)N/Ag composite exhibits a higher electri- cal conductivity of 1 106( Ohm · m) - 1 and thermal conductivity of 10.5 W/(inK) than that of Mn3(Cu0.6Si0.15Ge0.25)N.