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水蒸气活化制备烟杆基颗粒活性炭的研究
  • ISSN号:1001-5493
  • 期刊名称:《离子交换与吸附》
  • 时间:0
  • 分类:TQ424.1[化学工程]
  • 作者机构:[1]昆明理工大学材料与冶金工程学院,昆明650093
  • 相关基金:国家自然科学基金(项目编号:20167001)
中文摘要:

以烟杆废弃物为原料,以木焦油为主的复合粘结剂,通过水蒸气活化制备了烟杆基颗粒活性炭。对影响颗粒活性炭吸附性能和收率的因素如活化温度、活化时间、水蒸气流量进行了系统研究,得到了最佳工艺条件:活化温度为900℃,活化时间为60mim,水蒸气流量为3.31g/min。该工艺条件下,烟杆基颗粒活性炭对碘的吸附值为1028mg/g,对亚甲基蓝的吸附值为285mg/g,收率为24.39%。同时,测定了该活性炭氮吸附,通过BET计算了活性炭的比表面积,并通过密度函数理论(DFT)表征了活性炭的孔结构。结果表明,该活性炭为微孔型,BET比表面积为1073m^2/g,总孔容为0.8152ml/g。

英文摘要:

A series of granular activated carbons were prepared, using tobacco stems as materials, wood tar as the mainly binder and steam as the activation agent. The effect of process variables such as activation temperature, activation time and flow rate of steam on yield and adsorption properties was systematically studied. The optimum preparation parameters were obtained as follows: activation temperature was 900℃, activation time was 60 minutes and flow rate of steam was 3.31g/min. The yield of the granular activated carbon was 24.39% when the methylene blue adsorption reached 285mg/g and the iodine number was 1028mg/g. Furthermore, the granular activated carbon in optimum condition was characterized by N2 adsorption at 77K, using the BET and DFT methods. The BET surface area and pore volume were 1073m^2/g and 0.8152mL/g, respectively. It shown that the granular activated carbon possessed predominant microporous structures.

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期刊信息
  • 《离子交换与吸附》
  • 北大核心期刊(2011版)
  • 主管单位:教育部
  • 主办单位:南开大学
  • 主编:张全兴
  • 地址:天津南开大学
  • 邮编:300071
  • 邮箱:LZJHYXF@NANKAI.EDU.CN
  • 电话:022-23503511
  • 国际标准刊号:ISSN:1001-5493
  • 国内统一刊号:ISSN:12-1147/O6
  • 邮发代号:6-57
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:8646