将粒子示踪(particle tracking velocimetry,PTV)技术与高温锥板一平板流变仪结合,研究了聚氧化乙烯(poly(ethylene oxide),PEO)熔体的延迟壁滑行为.当高于某一临界应变时,PEO熔体在剪切停止后,上板壁附近呈现宏观运动.这是首次利用高温PTV装置观测到延迟壁滑现象.延迟壁滑现象无法用deGennes的壁滑模型解释,但可以用王十庆提出的分子理论解释.
The delayed slip behavior of entangled poly(ethyiene oxide) (PEO) melts was studied by means of the particle tracking velocimetric (PTV) technique in a high temperature cone-plate geometry. The PEO melts exhibited macroscopic motions near the top wall after shear cessation, when the imposed strain was larger than a critical value. It is the first time that delayed slip was observed with a high-temperature PTV device. This delayed slip behavior cannot be explained by de Gennes slip model, but can be rationalized by Wang's molecular theory.