以端乙烯基硅油为基胶、含氢硅油为交联剂、r-甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)为表面处理剂、A1(OH),或AI(OH)3/铂络合物为阻燃剂,制备阻燃型有机硅电子灌司胶。研究结果表明:对AI(OH),表面进行处理、降低其粒径、增加其含量、A1(OH)3/铂络合物并用等均有利于提升灌封胶的阻燃性能;当W(KH-570)=0.5%[相对于A1(OH)3质量而言]、A1(OH)。的平均粒径为2.6μm、m(5.0μmA1203):m2.6μmA1(OH),]=160:40和W(铂络合物)=0.002%(相对于基胶质量而言)时,可制得阻燃性优异的有机硅电子灌封胶。
With a vinyl-terminal silicon oil as matrix ,a silicon oil containing hydrogen as cross hnker, a r-methacryloxypropyltrimethoxysilane (KH-570) as surface treatment agent, A1 ( OH ) 3 or A1 (OH) 3/platinum complex compound as flame retardants,an organosilicon electronic-pouring sealant with flame-retardant was prepared. The research results showed that the flame-retardant of pouring sealant could all be enhanced by following methods such as surface treatment of Al(OH)3,reducing its particle sizes and increasing its contents, using Al(OH)3/platinum complex compound,and other methods. The organosilieon electronic-pouring sealant had excellent flame-retardant when mass fraction of KH-570 was 0.5% in Al(OH)3,the average particle size of AI(OH)3 was 2.6 Ixm,mass ratio of m(5.0 μm A1203):m[2.6 μm AI(OH)3] was 160:40,and mass fraction of platinum complex compound was 0.002% in matrix.