欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
水热条件下,以磷酸H3PO4和亚磷酸H3PO3与Mn（Ⅱ）盐进行反应,以四甲基氢氧化铵（TMAOH）调节溶液酸度得到三维开放骨架结构化合物[Mn2.5（PO4H）2（OH）（H2O）]（1）.对化合物1进行了单晶X射线衍射分析、粉末X射线衍射分析（XRD）、元素分析及红外分析（IR）.单晶结构分析表明,该化合物属单斜晶系,C2/c空间群,晶胞参数a=1.763 19（7）nm,b=0.915 12（4）nm,c=0.950 74（6）nm,β=96.565（3）°,V=1.524（1）nm3,Z=4,Dc=3.176 g/cm3,Mr=728.66,μ=4.566 mm-1,R=0.024 5,ωR=0.084 8[I〉2sigma（I）].
英文摘要：
A new three-dimensional framework,[Mn2.5（PO4H）2（OH）（H2O）]（1）,was synthesized under the hydrothermal condition.Its structure was determined by single crystal X-ray diffraction analysis and further characterized by XRD,and elemental analysis.The compound 1 crystallizes in monoclinic space group C2/c,with a=1.763 19（7） nm,b=0.915 12（4） nm,c=0.950 74（6） nm,β=96.565（3）°,V=1.524（1） nm3,Z=4,DC=3.176 g/cm3,Mr=1457.32,μ=4.566 mm-1,R=0.024 5,ωR=0.084 8[I〉2sigma（I）].
同期刊论文项目
同项目期刊论文
Modulate the phase transition temperature of hydrogels with both thermosensitivity and biodegradabil
Synthesis, Structures and Photoluminescent Properties of Two Novel Zinc(II) Compounds Constructed fr
Synthesis and characterization of thermosensitive graft copolymer of N -isopropylacrylamide with bio
Covalent or not? Energy decomposition analysis of metal–metal bonding in alkaline-Earth dimetallocen
Theoretical investigation of electronic structures and excitation energies of hexaphyrin and its gro
THEORETICAL STUDIES ON EXCITED STATE PROTON TRANSFER TAUTOMERISM REACTION AND SPECTROSCOPIC PROPERTI
Synthesis, crystal structures and density functional theory study of dimeric copper(II) complexes of
Synthesis, characterization and spectra studies on Zn(II) and Cu(II) complexes with thiocarbamide li
Synthesis, Crystal Structure and Properties of 10-(4,5-Dibenzylthio- 1,3-dithiol-2-ylidene)anthracen
Electronic Structures and Spectra of Porphyrin With Fused Benzoheterocycles: DFT and TDDFT-PCM Inves
Direct electron transfer and bioelectrocatalysis of hemoglobin on nano-structural attapulgite clay-m
期刊信息
位置：