中文摘要：

在水热条件下,用Cu（Ⅱ）盐与邻菲罗啉（phen）进行反应,得到了三维超分子[Cu2（phen）2（H2O）4].（SO4）2（化合物1）.化合物1为单斜晶系,C2/c空间群,晶胞参数：a=4.233（2）nm,b=1.3844（8）nm,c=0.7025（4）nm,β=90.230（7）°,V=4.117（4）nm3,Z=8,R1=0.0898,ωR2=0.1566.化合物1中,两个中心Cu（II）离子均以四配位模式分别形成平面四边形单元[CuN2O2]2＋.配离子[CuN2O2]2＋与游离的SO42-离子通过静电引力、氢键和π—π堆积作用,将化合物1构筑成三维超分子.荧光测试结果表明,化合物1在270 nm的激发波长下于450 nm处呈现出荧光发射峰.

英文摘要：

The title compound [Cu2（phen）2（H2O）4]·（SO4）2 1 was isolated from hydrothermal synthesis of Cu（II） salt and 1,10-phen.It was characterized by X-ray single-crystal diffraction,XRD,element analysis and IR.X-ray single-crystal diffraction shows 1 belongs to monoclinic system,with space group C2/c,a=4.233（2） nm,b=1.3844（8） nm,c=0.7025（4） nm,β=90.230（7）°,V=4.117（4） nm3,Z=8,R1=0.0898,ωR2=0.1566.In 1,two central Cu2＋ ions adopt four coordination mode with two N atoms and two O atoms to form [CuN2O2]2＋ planar square.The coordination units [CuN2O2]n2＋ interconnected with the free SO2-4 ions to build a3-D supramolecular network by electrostatic attraction,hydrogen bonds,π—π stacking interactions.The solid-state fluorescent property of 1 at room temperature shows compound 1 possesses a fluorescent emission band at λem=450 nm（λex=270 nm）.