阴丹士林出众的格林 FFB (数据块间隔) 的间接电气化学的减小被周期的 voltammetry 和电解实验详细调查。Triethanolamine (茶) 被用作 ligand 形成电气化学地活跃的 Fe (III ) 在碱的答案的建筑群。包括反应温度操作参数的效果,当前的密度, NaOH 和 Fe (III ) 的集中茶调停人被直角的实验学习了,电气化学的减小上的激进分子的机制被讨论。Fe (III ) 茶建筑群好的试验性的结果表演为数据块间隔的间接电气化学的减小适合的周期的 voltammetry。高当前的效率(49.9%) 罐头成功地被完成在下面的电解实验表演优化了条件,当前的密度被发现是主要影响因素。
The indirect electrochemical reduction of Indanthrene Brilliant Green FFB (IBG) was investigated in detail by cyclic voltammetry and electrolytic experiments.Triethanolamine (TEA) was used as ligand to form elec-trochemically active Fe(III)-complexes in alkaline solution.The effects of operating parameters including reaction temperature,current density,concentration of NaOH and Fe(III)-TEA mediator had been studied by orthogonal ex-periments and the mechanism of radicals on electrochemical reduction was discussed.The cyclic voltammetry ex-perimental results show that Fe(III)-TEA complexes are well suited for the indirect electrochemical reduction of IBG.The electrolytic experiments show that high current efficiency (49.9%) can be successfully achieved under op-timized conditions and the current density is found to be the main influence factor.