采用氮化铝(A1N)和纳米氮化铝(n-A1N)、二氧化硅(SiOz)以及经过硅烷偶联剂(KH560)处理的A1N和Si02与氰酸酯(cE)树脂共混,设计制备了AlN/cE,n-A1N/CE,A1N—SiOz/CE和A1N(KH560)一SiOz(KH560)/CE复合材料。研究了填料的种类、粒径、含量和表面性质对复合材料导热性能、介电性能的影响。结果表明:填料对复合材料的导热性能有显著影响,用n_A1N和A1N混合填充CE,不同粒径的A1N可以形成紧密堆砌而提高热导率A。高含量的A1N添加到CE中会提高复合材料的介电常数,但将SiO:部分取代A1N,能减少介电常数的增加量。
Three composites based on CE resin, aluminum nitride (AIN), nano A1N (n-A1N) and sili- con dioxide (SiO2), and silane coupling agent (KH560) modified A1N and SiO2 ,coded as A1N/CE, n-A1N/CE, A1N-SiO2/CE and A1N(KH560)-SiO2 (KH560)/CE composite, respectively, were pre- pared. The influences of the sort, size and surface nature of fillers on the thermal conductivity and die- lectric properties of composites were investigated in detail. The results show that properties of fillers have great influence on the thermal conductivity of composites. When CE resin was filled by n-A1N and A1N,the resultant composites increased thermal conductivity due to the close arrangement. The composite with a higher content of A1N had higher dielectric constant. But when SiO2 was used to re- place A1N,the increasement of dielectric constant was reduced.