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球状β-FeOOH对卷烟主流烟气中烟草特有N-亚硝胺的影响研究
  • ISSN号:1004-5708
  • 期刊名称:《中国烟草学报》
  • 时间:0
  • 分类:TS411[农业科学—烟草工业;轻工技术与工程]
  • 作者机构:[1]中国烟草总公司郑州烟草研究院,郑州高新技术产业开发区枫杨街2号450001, [2]红塔烟草(集团)有限责任公司,云南省玉溪市红塔大道118号653100
  • 相关基金:国家自然科学基金项目“新型层状氢氧化物微结构组装体的水相合成、形成机理及应用研究”(20701040)
中文摘要:

通过液相方法合成了球状β-FeOOH,利用FE-SEM、BET、XRD、IR,XPS等手段对其进行的表征显示产物为球状聚集体,单个球体的直径约为1μm。将其加入到卷烟烟丝和模拟滤嘴装置中研究其对主流烟气中4种烟草特有N-亚硝胺释放量的影响,并考察其对部分卷烟烟气特征参数、燃烧性能和烟丝常规化学成分的影响。结果表明:①10mg/支的量湿法加入到肯塔基参比卷烟(1RSF)烟丝中,主流烟气中的NNN、NNK、TSNAs总量分别降低41.3%、48.6%、36.1%;②加入到模拟滤嘴装置中,主流烟气中的NNN、NNK、TSNAs总量分别降低17.8%、36.8%、29.0%;③以10mg/支的量加入到选择的6种混合型卷烟中,主流烟气中的TSNAs均有不同程度的降低,而对焦油、CO、阴然速率和烟气常规化学成分等影响较小。

英文摘要:

Sphere-like β-FeOOH was successfully prepared via a liquid-phase method and FE-SEM, BET, XRD, IR and XPS were utilized to characterize the products. The sphere-like β-FeOOH was built up by several spheroids with a diameter of 1μm of each unitary spheroid. Effects of the synthesized β-FeOOH on four TSNAs (tobacco special nitrosamines, NNN, NAN, NAB, NNK) in mainstream smoke were studied. The as-prepared sphere-like β-FeOOH was added to cut tobacco of Kentucky reference cigarettes. Smoke analysis results showed that there was a distinct decrease for the TSNAs of Kentucky reference cigarettes. When the dosage was 10 mg/cig, the reducing efficiency of NNN, NNK, and total TSNAs was 41.3%, 48.6%, 36.1%, respectively. When sphere-like β-FeOOH was added in the simulative filter tips, the reducing efficiency of NNN, NNK and total TSNAs was 17.8 %, 36.8 % and 29.0 %, respectively. 10 mg/cig (optimized additive amount) of sphere-likeβ-FeOOH was employed in cut tobacco to produce six blended-type cigarettes. Different reducing efficiencies for TSNAs were obtained. Analysis of tar, nicotine, CO, burning speed, burning temperature and routine components showed that sphere-like β-FeOOH had little effects on feature parameters of smoke, burning performance and routine components in cut tobacco.

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期刊信息
  • 《中国烟草学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国烟草学会
  • 主编:袁行思
  • 地址:北京日坛南街55号
  • 邮编:100045
  • 邮箱:xh-bj@tobacco.gov.cn
  • 电话:010-63605768 63606237
  • 国际标准刊号:ISSN:1004-5708
  • 国内统一刊号:ISSN:11-2985/TS
  • 邮发代号:80-504
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),英国农业与生物科学研究中心文摘,荷兰文摘与引文数据库,美国工程索引,中国中国科技核心期刊,中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:9701