中文摘要：

甲壳素与苯基异氰酸酯衍生物（2a-2d）经氨基甲酰化反应合成了4个新型的甲壳素苯基氨基甲酸酯衍生物（3a-3d）,其结构经IR和元素分析表征。分别将3a-3c涂敷于大孔氨丙基硅胶表面（涂覆量均为16 wt%）制得相应的手性固定相（3a＇-3c＇）。3a＇-3c＇对19个手性化合物的分离性能和耐用性能研究结果表明：3a＇-3c＇的手性识别性能及耐用性均优于纤维素-三（3,5-二甲基苯基氨基甲酸脂）固定相。

英文摘要：

Four novel chitin derivatives （3a - 3d） were prepared by carbamoylation reaction of chitin with phenyl isocyanates. The structures were characterized by IR and elemental analysis. Three ehiral stationa- ry phases（3a＇ -3c＇） were obtained by coating 16 wt% 3a -3e on maeroporous silanized silica gel. The enantioseparation capabilities and durability of 3a＇ - 3c＇ were investigated by analysis on nineteen ehiral compounds. The results showed that ehiral recognition capability and high durability of3a＇ -3e＇ were better than the chiral stationary phase prepared from celhdose tris（3,5-dimethylphenylcarbamate）.