中文摘要：

<正> Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatmentis presented,using a nanosecond-positive-edge repetitive pulsed dielectric barrier dischargegenerator in atmospheric air.The electrical parameters including discharging power,peak anddensity of micro-discharge current were calculated,and the electron energy was estimated.Surfacetreatment experiments of polytetrafluoroethylene films were conducted for both differentapplied voltages and different treating durations.Results show that the surface energy of polytetrafluoroethylenefilm could be improved to 40 mJ/m~2 or more by plasma treatment.Surfaceroughness measurement and surface X-ray photoelectron spectroscopy analysis indicate that thereare chemical etching and implantation of polar oxygen groups in the sample surface treating process,resulting in the improvement of the sample surface energy.Compared with an AC sourceof 50 Hz,the dielectric barrier discharges generated by a repetitive pulsed source could providehigher peak power,lower mean power,larger micro-discharge current density and higher electronenergy.Therefore,with the same applied peak voltage and treating duration,the improvementof polytetrafluoroethylene surface energy using repetitive pulsed plasma is more effective,and theplasma treatment process based on repetitive pulsed dielectric barrier discharges in air is thusfeasible and applicable.

英文摘要：

Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatment is presented, using a nanosecond-positive-edge repetitive pulsed dielectric barrier discharge generator in atmospheric air. The electrical parameters including discharging power, peak and density of micro-discharge current were calculated, and the electron energy was estimated. Surface treatment experiments of polytetrafluoroethylene films were conducted for both different applied voltages and different treating durations. Results show that the surface energy of polytetrafluoroethylene film could be improved to 40 mJ/m2 or more by plasma treatment. Surface roughness measurement and surface X-ray photoelectron spectroscopy analysis indicate that there are chemical etching and implantation of polar oxygen groups in the sample surface treating process, resulting in the improvement of the sample surface energy. Compared with an AC source of 50 Hz, the dielectric barrier discharges generated by a repetitive pulsed source could provide higher peak power, lower mean power, larger micro-discharge current density and higher electron energy. Therefore, with the same applied peak voltage and treating duration, the improvement of polytetrafluoroethylene surface energy using repetitive pulsed plasma is more effective, and the plasma treatment process based on repetitive pulsed dielectric barrier discharges in air is thus feasible and applicable.