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Photovoltaic Properties of the Modified n-Si(111) Electrodes with Ethyl and Carboxyls
  • 时间:0
  • 分类:TM0[电气工程—电工理论与新技术]
  • 作者机构:[1]State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China, [2]College of Science, Beijing University of Chemical Technology, Beijing 100029, China
  • 相关基金:Acknowledgements We are grateful to the Project of the National Natural Science Foundation of China(Grant No.50602004),the support from Chinese Education for Back Student Abroad and the fund for Young Teacher of BUCT (Project No.QN0512) for financial support.
  • 相关项目:尖晶石型铁氧体在单晶硅表面上的定向接枝及复合半导体的光电转化效应
中文摘要:

n-Si (111 ) 表面跟踪 -C2H5,-C2H4COOH,-C2H2COOH 被反应在 Si-H 之中准备到 ethyl-Grignard,甲基压克力吃了,丙酸乙酯,和 carboxyls 在 trifluoroacetic 酸的存在下面被形成。合成 n-Si (lll ) 电极被扔磅 nanodots 获得,为这些电极的光电的特征在 I~-/I_3~- 氧化还原作用电解质被学习。到在太阳的照明下面的电极的相片电压和光电流密度的行为与一些 -C2H2COOH>-C2H4COOH>-H>-C2H5.The 相片电压和电极的光电流密度一起定期改变了的 j-U (相片水流密度潜力) 跟踪了 -C2H2COOH 分别地,是 -0.641 V 和 5.25 mA/cm2 比那些更否定非结合的修正。

英文摘要:

n-Si(111) surface tailed -C2H5, -C2H4COOH, -C2H2COOH were prepared by the reactions among Si-H to ethyl-Grignard, methyl acrylate and ethyl propionate, and the carboxyls were formed under the existence of trifluoroacetic acid. The composite n-Si(111) electrodes were obtained by depositing Pt nanodots and the photovoltaic characteristics for these electrodes were studied in I^-/I3^- redox electrolyte. The j-U (photo current density-potential) behaviors of photo-voltage and photocurrent densities to the electrodes under solar illumination varied regularly with groups of -C2H2COOH〉-C2H4COOH〉-H〉-C2H5. The photo-voltage and photocurrent density of the electrode tailed -C2 H2COOH were -0.641 V and 5.25 mA/cm^2, respectively, more negative than those of the non-conjugated modification.

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