通过射频磁控溅射法和脉冲激光沉积法,以Ti—Al为阻挡层,在(001)Si衬底上制备了La0.5Sr0.5CoO3(LSCO)/Na0.5Bi0.5TiO3(NBT)/LSCO(LSCO/NBT/LSCO)异质结铁电电容器。研究了Na0.5Bi0.5TiO3铁电薄膜的结构和物理性能。结果表明:Ti—Al阻挡层为非晶结构,NBT薄膜结晶质量良好。在1500kV/cm驱动电场下,LSCO/NBT/LSCO电容器呈现饱和的电滞回线,具有较大的剩余极化强度(47.9μC/cm^2)和较小的脉宽依赖性,而且抗疲劳特性和保持特性良好。此外,漏电机制研究表明:当外加电场小于400kV/cm时,LSCO小BT/LSCO电容器满足欧姆导电机制,在电场大于400kV/cm时,满足空间电荷限流传导机制。
La0.5Sr0.5CoO3(LSCO)/Na0.5Bi0.5TiO3/La0.5Sr0.5CoO3 (LSCO/NBT/LSCO) ferroelectric capacitor heterostructure was fabricated on (001)Si substrate with amorphous Ti-Al film as a diffusion barrier layer, in which the LSCO and Ti-A1 films both were prepared by magnetron sputtering (MS), and the NBT was prepared by a pulsed laser deposition method (PLD). The structural and physical properties of Na0.5Bi0.5TiO3 film were characterized. The results show that the Ti-Al barrier is amorphous, and the NBT film consists of the crystallines. The LSCO/NBT/LSCO capacitor presents a saturated hysteresis loop, a high remnant polarization (i.e., 47.9 μC/cm^2), a small pulse width dependence, good fatigue and retention characteristics at an applied field of 1 500 kV/cm. Moreover, the leakage mechanism of the LSCO/NBT/LSCO ferroelectric capacitor was investigated. The LSCO/NBT/LSCO capacitor has the Ohm conduction behavior at applied fields of 〈 400 kV/cm and bulk-limited space charge-limited conduction (SCLC) at the applied fields of〉 400 kV/cm.